190328-51-9Relevant academic research and scientific papers
Cyano-activated fluoro displacement reactions in the synthesis of cyanophenoxazines and related compounds
Eastmond,Gilchrist,Paprotny,Steiner
, p. 385 - 390 (2007/10/03)
Cyano-activated fluoro displacement reactions between 2,3- and 3,4-difluorobenzonitriles and the nucleophiles catechol, 2-aminophenol, 2-aminobenzenethiol and benzene-1,2-dithiol either in DMF at 130°C or in DMSO at rt, in the presence of potassium carbon
A Facile Synthesis of Cyanophenothiazines
Marivingt-Mounir, Cecile,Mettey, Yvette,Vierfond, Jean-Michel
, p. 843 - 845 (2007/10/03)
A one-pot synthesis of 1, 3 and 4-cyanophenothiazines and a two-step approach to 2-cyanoisomer have been developed. The condensation of 2-aminobenzenethiol and 2,3 or 3,4-dihalogenobenzonitriles followed by Smiles rearrangement or by intramolecular aromatic substitution gave the desired ring systmes.
Synthesis of 11-Aminodibenzo[b,f][1,4]thiazepines and Fluoro Derivatives
Mettey, Yvette,Lehuede, Jacques,Vierfond, Jean-Michel
, p. 465 - 467 (2007/10/03)
The reaction of halogenobenzonitriles with 2-aminobenzenethiol is a new route, in a "one-pot" or two-step approach, to 11-aminodibenzo[b,f][1,4]thiazepine and fluoro derivatives.
