190439-86-2

Upstream product

• 496-72-0 4-methyl-1,2-diaminobenzene 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 257630-78-7 [CH₃C₆H₃(NHP(C₆H₅)2AuC₆F₅)2] 
• 190439-95-3 cis-Mo(CO)4[P(C₆H₅)2NH]2C₆H₃CH₃ 
• 257630-92-5 [CH₃C₆H₃(NHP(C₆H₅)2)(NHP(C₆H₅)2Au(C₆F₅)3)] 
• 257630-96-9 [CH₃C₆H₃(NHP(C₆H₅)2)2Au(C₆F₅)3AuC₆F₅] 
• 257630-94-7 [CH₃C₆H₃(NHP(C₆H₅)2)2Au(C₆F₅)3AuCl] 
• 190440-02-9 [(AuCl)2(CH₃C₆H₃(NHP(C₆H₅)2)2)] 

Relevant academic research and scientific papers

Synthesis, co-ordination chemistry and crystallographic studies of some bis(aminophosphines)

l,2-Bis(diphenylphosphinoamino)benzene 1 and 3,4-bis(diphenylphosphinoamiho)toluene 2 have been prepared; 1 is oxidised by sulfur or selenium to C6H4(NHPPh2S)2-l,2 3 and C6H4(NHPPh2Se)2-l,2 4 and by sulfur and selenium to C6H4(NHPPh2S)(NHPPh2Se)-l,2 5. The napthalene compounds C)0H6(NHPPh2S)2-l,8 6, CIOH6(NHPPh2Se)2-l,8 7, C10H6(NHPPh2S)(NHPPh2Se)-l,8 8 and the ethane compound C2H4(NHPPh2S)2-l,2 9 have also been prepared. The co-ordination of 2 to Mo°, Pd, Pt and Au1, i.e. in cw-[Mo(CO)4L], cw-[MC!2L] (M = Pd or Pt) and [(AuCl)2L] [L = MeC6H3(NHPPh2)2-3,4] is also described. The crystals structures of representative examples have been determined.