190439-95-3Relevant academic research and scientific papers
Synthesis, co-ordination chemistry and crystallographic studies of some bis(aminophosphines)
Ly, Tuan Q.
, p. 1611 - 1616 (2007/10/03)
l,2-Bis(diphenylphosphinoamino)benzene 1 and 3,4-bis(diphenylphosphinoamiho)toluene 2 have been prepared; 1 is oxidised by sulfur or selenium to C6H4(NHPPh2S)2-l,2 3 and C6H4(NHPPh2Se)2-l,2 4 and by sulfur and selenium to C6H4(NHPPh2S)(NHPPh2Se)-l,2 5. The napthalene compounds C)0H6(NHPPh2S)2-l,8 6, CIOH6(NHPPh2Se)2-l,8 7, C10H6(NHPPh2S)(NHPPh2Se)-l,8 8 and the ethane compound C2H4(NHPPh2S)2-l,2 9 have also been prepared. The co-ordination of 2 to Mo°, Pd, Pt and Au1, i.e. in cw-[Mo(CO)4L], cw-[MC!2L] (M = Pd or Pt) and [(AuCl)2L] [L = MeC6H3(NHPPh2)2-3,4] is also described. The crystals structures of representative examples have been determined.
