190599-46-3

Upstream product

• 190599-45-2 (2S,3R)-3-Benzyloxy-5,5-dimethoxy-pentane-1,2-diol 
• 100-39-0 benzyl bromide 
• 190599-44-1 Acetic acid (1S,2R)-1-acetoxymethyl-2-benzyloxy-4,4-bis-ethylsulfanyl-butyl ester 

Downstream Products

• 190599-53-2 Thioacetic acid S-((1R,2R)-2-benzyloxy-4,4-dimethoxy-1-methyl-butyl) ester 
• 190599-49-6 (S)-2-((R)-1-Benzyloxy-3,3-dimethoxy-propyl)-thiirane 
• 190599-51-0 (2R,3R)-3-Benzyloxy-5,5-dimethoxy-pentane-2-thiol 
• 190599-47-4 (S)-4-((R)-1-Benzyloxy-3,3-dimethoxy-propyl)-[1,3,2]dioxathiolane 2,2-dioxide 

Relevant academic research and scientific papers

Applications of Cyclic Sulfates of vic-Diols: Synthesis of Episulfides, Olefins, and Thio Sugars

A new efficient and expeditious one-pot synthesis of thiiranes and olefins from cyclic sulfates of inc-diols is described. Opening of cyclic sulfates with potassium thioacetate or potassium thiocyanate followed by treatment with sodium methoxide led to ep