190712-55-1Relevant academic research and scientific papers
trans-Chlorobis(diphenylglyoximato)(tri-n-butylphosphine)cobalt(III)
Barton,Major,Mihichuk,Robertson,Seip
, p. 568 - 570 (1997)
The Co atom in the title cobaloxime, [CoCl-(C14H11N2O2)2(C12H27P)], is octahedrally coordinated to the two bidentate diphenylglyoximato ligands, approximating a plane with the Cl and P atoms located above and below the plane. The diphenylglyoximato moieties are themselves bent 6.6(1) and 9.8(1)° from the central plane of the four N atoms by the bulk of the tri-n-butylphosphine ligand. The four phenyl rings of the two diphenylglyoximato groups form a propeller geometry with an average rotation from the central plane of 47(5)°.
