19075-34-4

Upstream product

• 2905-24-0 3-Bromobenzenesulfonyl chloride 
• 591-19-5 m-Bromoaniline 
• 2564-83-2 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical 
• 6320-01-0 3-Bromothiophenol 

Downstream Products

• 1359979-83-1 3-(2-oxo-propylsulfanyl)-benzoic acid methyl ester 
• 1359980-24-7 3-((6-chloro-2-methyl-1-phenyl-1H-indol-3-yl)thio)benzoic acid 
• 1359980-52-1 3-((6-chloro-2-methyl-1-(1-methyl-1H-pyrazol-4-yl)-1H-indol-3-yl)thio)benzoic acid 
• 1359979-87-5 3-(1-benzyl-2-methyl-6-phenyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 
• 1359979-85-3 3-(1-benzyl-6-bromo-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 
• 1359979-84-2 3-(6-bromo-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 
• 1359982-73-2 3-(6-cyano-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 
• 1359982-68-5 N-{3-[6-chloro-1-(1-ethyl-1H-pyrazol-4-yl)-7-fluoro-2-methyl-1H-indol-3-ylsulfanyl]-benzoyl}-methanesulfonamide 
• 1359979-82-0 3-(1-benzyl-6-bromo-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid 
• 1359979-75-1 3-((6-chloro-1,2-dimethyl-1H-indol-3-yl)thio)benzoic acid 
• 1359979-78-4 3-(6-chloro-1,2-dimethyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 
• 1359979-77-3 methyl 3-((6-chloro-2-methyl-1H-indol-3-yl)thio)benzoate 

Relevant academic research and scientific papers

Synthesis of α-arylthioacetones using TEMPO as the: C 3 synthon via a reaction cascade of sequential oxidation, skeletal rearrangement and C-S bond formation

Here, we present an unprecedented pathway to α-sulfenylated carbonyl compounds from commercially available thiols and universally employed TEMPO and its analogues, which act as C3 synthons through skeletal rearrangement under simple and metal-f