190900-55-1Relevant academic research and scientific papers
Rhodium(II)-catalyzed equilibration of push-pull carbonyl and ammonium ylides. A computationally based understanding of the reaction pathway
Padwa, Albert,Snyder, James P.,Curtis, Erin A.,Sheehan, Scott M.,Worsencroft, Kimberly J.,Kappe, C. Oliver
, p. 8155 - 8167 (2007/10/03)
Δ-Diazo esters containing an amido group in the γ-position have been found to undergo a rhodium(II)-catalyzed transformation, producing five-membered ammonium or carbonyl ylides depending on the reaction conditions used. In the absence of an external dipo
