191109-54-3Relevant academic research and scientific papers
Synthesis of novel C3 symmetric tris(thiazoline) ligands and their application in the allylic oxidation reaction
Cheng, Xue-Ming,Zheng, Zhong-Bo,Li, Nan,Qin, Zhao-Hai,Fu, Bin,Wang, Neng-Dong
experimental part, p. 2159 - 2163 (2009/04/11)
A series of novel C3 symmetric tris(thiazoline) ligands were synthesized from trimethyl nitrilotriacetate and an enantiomerically pure amino alcohol via an efficient route. Compound 7a showed moderate to good catalytic enantioselectivity for th
Enantioselective allylic oxidation of cycloalkenes by using Cu(II)-tris(oxazoline) complex as a catalyst
Kawasaki, Ken-Ichi,Katsuki, Tsutomu
, p. 6337 - 6350 (2007/10/03)
Optically active copper(II)-tris(oxazoline) complex that was synthesized as a model compound of the active site of non-heme oxygenase, was found to catalyze allylic oxidation of cycloalkenes to give the corresponding 2-cycloalkenyl benzoates with moderate to excellent enantioselectivity (up to 93% ee) under die Kharash-Sosnovsky reaction conditions.
