Cas 191112-16-0,Ti(C5(CH3)5)(OC6F5)2(1+)*CH3B(C6F5)3(1-) = [Ti(C5(CH3)5)(OC6F5)2]CH3B(C6F5)3

191112-16-0

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Basic information

Product Name: Ti(C₅(CH₃)5)(OC₆F₅)2⁽¹⁺⁾*CH₃B(C₆F₅)3^(1-) = [Ti(C₅(CH₃)5)(OC₆F₅)2]CH₃B(C₆F₅)3
Synonyms:
CAS NO:191112-16-0
Molecular Formula:
Molecular Weight: 1076.24
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: Ti(C₅(CH₃)5)(OC₆F₅)2⁽¹⁺⁾*CH₃B(C₆F₅)3^(1-) = [Ti(C₅(CH₃)5)(OC₆F₅)2]CH₃B(C₆F₅)3(CAS DataBase Reference)
NIST Chemistry Reference: Ti(C₅(CH₃)5)(OC₆F₅)2⁽¹⁺⁾*CH₃B(C₆F₅)3^(1-) = [Ti(C₅(CH₃)5)(OC₆F₅)2]CH₃B(C₆F₅)3(191112-16-0)
EPA Substance Registry System: Ti(C₅(CH₃)5)(OC₆F₅)2⁽¹⁺⁾*CH₃B(C₆F₅)3^(1-) = [Ti(C₅(CH₃)5)(OC₆F₅)2]CH₃B(C₆F₅)3(191112-16-0)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 191112-16-0(Hazardous Substances Data)

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191112-16-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 191112-16-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,9,1,1,1 and 2 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 191112-16:
(8*1)+(7*9)+(6*1)+(5*1)+(4*1)+(3*2)+(2*1)+(1*6)=100
100 % 10 = 0
So 191112-16-0 is a valid CAS Registry Number.

191112-16-0Relevant academic research and scientific papers

Solution structures and exchange phenomena of the new alkene polymerization initiators (η-C5Me5)TiMe(E)(μ-Me) B(C6F5)3 (E = C6F5, OC 6F5) and [(η-C5

Tremblay, Tracey L.,Ewart, Sean W.,Sarsfield, Mark J.,Baird, Michael C.

, p. 831 - 832 (1997)

The solution structures and dynamics of the new alkene polymerization initiators (η-C5Me5)TiMe(C6F 5)(μ-Me)B(C5F5)3 2, (η-C5Me5)TiMe(OC6F 5

Synthesis of a series of new, highly electrophilic, monocyclopentadienyltitanium olefin polymerization initiators

Sarsfield, Mark J.,Ewart, Sean W.,Tremblay, Tracey L.,Roszak, Aleksander W.,Baird, Michael C.

, p. 3097 - 3104 (2007/10/03)

The new compounds Ti(η-C5Me5)Me2E (E = C6F5 or OC6F5) and Ti(η-C5Me5)Me(OC6F5)2 have been synthesized and characterized by a variety of techniques, including 47/49Ti NMR spectroscopy. All three compounds react with the borane B(C6F5)3 to form the highly electrophilic but thermally unstable species Ti(η-C5Me5)Me(E)(η-Me)B-(C6F 5)3 and [η-C5Me5)Ti(OC6F5) 2][BMe(C6F5)3], the solution structures and dynamics of which are investigated and compared with those of the known compound Ti(η-C5Me5)Me2(η-Me)B(C 6F5)3,. Interestingly, Ti(η-C5Me5)-Me(C6F 5)(η-Me)B(C6F5)3 undergoes neither significant ion-pair dissociation to the solvent separated ions [(η-C5Me5)TiMe(C6F5)] + and [BMe(C6F5)3]- nor borane dissociation to its precursors (η-C5Me5)TiMe2(C6F5) and B(C6F5)3; indeed, both rotation about the Ti-C6F5 bond and inversion at the chiral metal are slow on the NMR time-scale. In contrast, Ti(η-C5Me5)Me(OC6F 5)(η-Me)B(C6F5)3 is more labile and, like Ti(η-C5Me5)Me2;(η-Me)-B(C 6F5)3, undergoes ion-pair dissociation, while [(η-C5Me5)Ti(OC6F5) 2][BMe(C6F5)3] exists in solution as the solvent separated ion species [(η-C5Me5)Ti(OC6F5) 2]- and [BMe(C6F5)3]- in equilibrium with its precursors, (η-C5Me5)TiMe(OC6F5)2 and B(C6F5)3.