191278-06-5

Basic information

• Product Name: Acetic acid ((4S,5S)-2,2-dimethyl-5-pentyl-[1,3]dioxolan-4-yl)-phenylsulfanyl-methyl ester
• CAS NO: 191278-06-5
• Molecular Weight: 352.495
• Mol File: 191278-06-5.mol

Chemical Properties

• CAS DataBase Reference: Acetic acid ((4S,5S)-2,2-dimethyl-5-pentyl-[1,3]dioxolan-4-yl)-phenylsulfanyl-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid ((4S,5S)-2,2-dimethyl-5-pentyl-[1,3]dioxolan-4-yl)-phenylsulfanyl-methyl ester(191278-06-5)
• EPA Substance Registry System: Acetic acid ((4S,5S)-2,2-dimethyl-5-pentyl-[1,3]dioxolan-4-yl)-phenylsulfanyl-methyl ester(191278-06-5)

Safety Data

• Hazardous Substances Data: 191278-06-5(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 18409-17-1 (E)-oct-2-en-1-ol 
• 191278-04-3 (2S,3S)-1-(phenylthio)-2,3-octanediol 
• 144482-30-4 (2S,3S)-1-(phenylthio)-2,3-isopropylidenedioxyoctane 
• 191277-94-8 tert-Butyl-dimethyl-[((E)-oct-2-enyl)oxy]-silane 
• 191278-02-1 (2S,3S)-1-(tert-Butyl-dimethyl-silanyloxy)-octane-2,3-diol 
• 191278-03-2 tert-Butyl-((4S,5S)-2,2-dioxo-5-pentyl-2λ⁶-[1,3,2]dioxathiolan-4-ylmethoxy)-dimethyl-silane 
• 930-69-8 sodium thiophenolate 

Relevant articles and documents

Synthesis of all four isomers of (E)-4,5-dihydroxydec-2-enal using osmium-catalysed asymmetric dihydroxylation

The enantioselective synthesis of the four possible isomers of (E)-4,5-dihydroxydec-2-enal, a cytotoxic product formed in peroxidised liver microsomal lipids, is accomplished via a Sharpless AD reaction alone or associated as appropriate with a regioselective epimerisation of one of the introduced hydroxy groups.