191355-78-9

Upstream product

• 141546-64-7 1D-(1,2,3,5/4,6)-1,2-O-isopropylidene-3-methyl-4-O-methylcyclohexane-1,2,3,4,5-pentol 
• 191355-74-5 3-deoxy-3-methyl-4-O-methyl-6-O-(4-methylphenylsulfonyl)-1,2-O-(1-methylethylidene)-D-myo-inositol 
• 191355-75-6 1D-(1,2,3,4,5/6)-1,2-anhydro-3,4-O-isopropylidene-5-methyl-6-O-methylcyclohexane-1,2,3,4,6-pentol 
• 191355-76-7 4,6-deoxy-4,6-dimethyl-5-O-methyl-2,3-O-(1-methylethylidene)-D-allo-inositol 
• 98-88-4 benzoyl chloride 
• 191355-77-8 1-O-benzoyl-4,6-deoxy-4,6-dimethyl-5-O-methyl-2,3-O-(1-methylethylidene)-D-allo-inositol 

Downstream Products

• 191355-82-5 Toluene-4-sulfonic acid (2S,3R,4R)-4-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methoxy-2-methyl-pentyl ester 
• 191355-79-0 Benzoic acid (1S,2R,3R,4S)-5-hydroxy-1-hydroxymethyl-3-methoxy-2,4-dimethyl-pentyl ester 
• 151519-02-7 pironetin 

Relevant academic research and scientific papers

Total synthesis of (-)-PA-48153C (pironetin) utilising L-quebrachitol as a chiral building block

The chiral and stereoselective synthesis of (-)-PA-48153C (pironetin) 1, a novel immunosuppressant, is described; the acyclic portion possessing four contiguous chiral centres in 1 was constructed stereoselectively from L-quebrachitol and the 2-pyranone m