1914-64-3

Upstream product

• 90050-63-8 bromo-phenylsulfanyl-acetic acid 
• 3959-08-8 (phenylsulfinyl)acetic acid 
• 108-98-5 thiophenol 
• 563-96-2 2,2-dihydroxyacetic acid 
• 60178-25-8 ethyl α-chloro-α-(phenylthio)acetate 
• 79-43-6 dichloro-acetic acid 
• 139-02-6 sodium phenoxide 
• 7605-25-6 ethyl phenylsulfenylacetate 
• 103-04-8 (phenylthio)acetic acid 
• 20461-96-5 ethyl α,α-bis(phenylthio)acetate 

Downstream Products

• 3561-67-9 bis(phenylthio)methane 
• 3406-02-8 bis(phenylsulfonyl)methane 
• 133901-72-1 N-Methyl-2,2-bis(phenylthio)-N-acetamide 
• 98834-76-5 Bis-phenylsulfanyl-acetyl chloride 
• 133901-76-5 N-Methyl-2-phenylthio-N-acetamide 
• 133901-56-1 3,4,5,6-Tetrahydro-1-methyl-3-phenylthio-1-benzazocin-2(1H)-one 
• 1537905-26-2 4-(4-methanesulfonylphenyl)-6-(trifluoromethyl)-2H-pyran-2-one 
• 24210-62-6 Phenylthiodifluor-N,N-diaethylacetamid 
• 98834-83-4 4-Bis-2-t-butyl-3-phenyl-1,2,4-oxadiazolidin-5-one 
• 98834-80-1 N-Phenyl-N'-(bismethyl)-urea 
• 98834-87-8 N-Bis(phenylthio)methyl-2-formylisobutyramide 
• 98834-77-6 Bisacetyl azide 
• 98834-75-4 Bismethyl isocyanate 
• 187869-29-0 2,2-bis(phenylthio)-N-[o-(prop-2-enyl)phenyl]acetamide 

Relevant academic research and scientific papers

Highly selective electrochemical fluorination of dithioacetal derivatives bearing electron-withdrawing substituents at the position α to the sulfur atom using poly(HF) salts

Anodic fluorination of dithioacetals bearing electron-withdrawing ester, acetyl, amide, and nitrile groups at their α-positions was comparatively studied using various supporting poly(HF) salts like Et3N·nHF (n = 3-5) and Et4NF·nHF (

Isothiourea-mediated one-pot synthesis of trifluoromethyl substituted 2-pyrones

A one-pot isothiourea-mediated Michael addition/lactonization/thiol elimination cascade sequence for the formation of 4,6-disubstituted and 3,4,6-trisubstituted 2-pyrones from (phenylthio)acetic acids and α,β-unsaturated trifluoromethyl ketones is described. The synthesis of a COX-2 inhibitor and the wide-ranging derivatization of the 2-pyrone moiety to trifluoromethyl substituted aromatics and heteroaromatics is also disclosed.

Novel Alumina-catalysed Reactions of Arylthioalkyl Halides and Related Compounds

Arylthioalkyl halides of the type ArS(CH2)nCl (Ar = phenyl or substituted phenyl, n = 1-4) undergo rearrangement on heating with neutral alumina to 1,n-bis(arylthio)alkanes of type ArS(CH2)nSAr in high yield.Similar rearrangements occur with some closely related structural types.The bis(arylthio)alkanes undergo further reaction with alumina at higher temperatures in air giving diaryl disulphides.Bis(o-iodophenylthio)methane eliminates iodine on heating with alumina, producing dibenzodithiepin.Some observations concerning the mechanism are presented.

A NOVEL AND CONVENIENT SYNTHESIS OF BISMETHANES

Bismethanes are produced in high yield on treatment of aryl chloromethyl sulphides with neutral alumina.