191542-42-4

Basic information

• Product Name: 1-<5-(phenylselanyl)pentyl>-2-tosyl-1H-imidazole
• Synonyms: 1-<5-(phenylselanyl)pentyl>-2-tosyl-1H-imidazole
• CAS NO: 191542-42-4
• Molecular Weight: 447.46
• Mol File: 191542-42-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-<5-(phenylselanyl)pentyl>-2-tosyl-1H-imidazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-<5-(phenylselanyl)pentyl>-2-tosyl-1H-imidazole(191542-42-4)
• EPA Substance Registry System: 1-<5-(phenylselanyl)pentyl>-2-tosyl-1H-imidazole(191542-42-4)

Safety Data

• Hazardous Substances Data: 191542-42-4(Hazardous Substances Data)

Upstream product

• 455-16-3 p-toluenesulfonyl fluoride 
• 223927-72-8 1-chloro-5-(phenylselanyl)pentane 
• 191542-49-1 2-tosyl-1-(triphenylmethyl)-1H-imidazole 
• 1666-13-3 diphenyl diselenide 
• 60274-60-4 1-chloro-5-iodopentane 
• 223927-75-1 5-iodo-1-(phenylselanyl)pentane 
• 205253-29-8 p-toluenesulfonyl imidazole 

Downstream Products

• 5768-55-8 2,3,4,6,7,8,9,10-octahydropyrimido<1,2-a>azepino 

Relevant articles and documents

Radical cyclisation onto imidazoles and benzimidazoles

New synthetic methodology has been developed for the synthesis of [1,2- a]fused imidazoles and benzimidazoles using intramolecular homolytic aromatic substitution. In the intramolecular substitution, N-(ω-alkyl) radicals are generated using Bu3SnH from N-(ω-phenylselanyl)alkyl side chains. Phenylselanyl groups are used as radical leaving groups to avoid problems in the N-alkylation of imidazoles and benzimidazoles. Arylsulfones for imidazoles, and phenylsulfides for benzimidazoles, are used at the leaving groups in the homolytic substitutions.