191591-48-7Relevant academic research and scientific papers
Fluorinated vinyl oxiranes
-
, (2008/06/13)
A compound having the formula: STR1 wherein: R is fluorine, hydrogen, an unsubstituted or substituted aliphatic or unsubstituted or substituted aromatic radical; R1 is an unsubstituted or substituted aliphatic radical, or unsubstituted or substituted aromatic radical; and R2 is hydrogen, an unsubstituted or substituted aliphatic radical, or unsubstituted or substituted aromatic radical.
1,3-Dichloro-4,4,4-trifluorobut-2-ene as a 4-carbon building block containing a trifluoromethyl group
Van Der Puy, Michael
, p. 187 - 191 (2007/10/03)
The preparation, isomerization, and utility of CF3CCl=CHCH2Cl as a 4-carbon reagent for the incorporation of a trifluoromethyl group is described. The regiochemistry observed for charged intermediates derived from CF3CCl=CHCH2Cl was consistent with MNDO calculated partial charges at C-1 and C-3. The anion-stabilizing and cation-destabilizing effects of the trifluoromethyl group were dominant.
