191596-56-2Relevant academic research and scientific papers
Enantioselective acyclic stereoselection under catalyst control. 2. Asymmetric synthesis of syn- and anti-1,3-diols incorporating an acetate equivalent by the chiral oxarzaborolidinone-catalyzed aldol reaction
Kiyooka, Syun-Ichi,Yamaguchi, Takafumi,Maeda, Hirofumi,Kira, Haruhide,Hena, Mostofa Abu,Horiike, Michio
, p. 3553 - 3556 (2007/10/03)
The chiral oxazaborolidinone-catalysed aldol reaction of a silyl ketene acetal involving a dithiolane moiety with β-silyloxy aldehyde resulted in the production of syn- and anti-1,3-diols with complete stereoselection by the choice of the stereochemistry of the catalyst. This reaction is an elegant example of enantioselective acyclic stereoselection under catalyst control.
