191614-60-5Relevant academic research and scientific papers
Hydroxyl-directed stereocomplementary pinacol cyclizations mediated by SmI2
Kawatsura,Kishi,Kito,Sakai,Shirahama,Matsuda
, p. 479 - 480 (1997)
The decalin rings were cyclized with complete stereocontrol about the new chiral centers through the hydroxyl-directed pinacol couplings promoted by SmI2. In these annulation reactions, stereocomplementarity was observed depending on the absence or presence of HMPA.
