Hydroxyl-directed stereocomplementary pinacol cyclizations mediated by SmI2

DOI: 10.1055/s-1997-6153

Source and publish data:

Synlett p. 479 - 480 (1997)

Update date:2022-07-29

Topics:

Authors:

Kawatsura

Kishi Kishi

Kito Kito

Sakai Sakai

Shirahama

Matsuda Matsuda

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Article abstract of DOI:10.1055/s-1997-6153

The decalin rings were cyclized with complete stereocontrol about the new chiral centers through the hydroxyl-directed pinacol couplings promoted by SmI₂. In these annulation reactions, stereocomplementarity was observed depending on the absence or presence of HMPA.

Full text of DOI:10.1055/s-1997-6153

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