191669-93-9Relevant academic research and scientific papers
Synthesis and crystal structure of [U(η-C5Me5) 2(OC4H8) 2][BPh4], the first cationic cyclopentadienyl compound of uranium(III)
Boisson, Christophe,Berthet, Jean Claude,Ephritikhine, Michel,Lance, Monique,Nierlich, Martine
, p. 7 - 11 (1997)
The mixed amide complexes [U(NEt2)2(N{SiMe3}2)2] and [U(η-C8H8)(NEt2)(N{SiMe3}2)] reacted in tetrahydrofuran (THF) with NEt3HBPh4
Multiple syntheses of (C5Me5)3U
Evans, William J.,Nyce, Gregory W.,Forrestal, Kevin J.,Ziller, Joseph W.
, p. 1050 - 1055 (2008/10/08)
Several new synthetic routes to the sterically crowded (C5Me5)3U complex have been developed. (C5Me5)3U can be prepared by (a) reaction of [(C5Me5)2UH2]2 with tetramethylfulvene, (b) reduction of (C5Me5)2Pb with (C5Me5)2UH(DMPE), (c) reaction of [(C5Me5)2U(L)]+ (L = THF, DMPE) with K(18-crown-6)(C5Me5), and (d) reaction of [(C5Me5)2U] [BPh4] with KC5Me3. Reaction of (C5Me5)2UH(DMPE) with C8H8 forms the product of the (C5Me5)3U/ C8H8 reaction, [(C8H8)(C5Me5)U]2(C8 H8). The X-ray crystal structures of the (C5Me5)2U[N(SiMe3)2] and [(C5Me5)2U] [BPh4] precursors used in this study are reported, as well as the convenient synthesis of a new trivalent uranium precursor, (C5Me5)2UMe2K.
