191719-98-9Relevant academic research and scientific papers
Construction of 1,3-oxathiane ring through Pummerer reaction of γδ- unsaturated sulfinyl compounds
Abe, Hitoshi,Fujii, Hiroyuki,Masunari, Chieko,Itani, Junko,Kashino, Setsuo,Shibaike, Kentaro,Harayama, Takashi
, p. 778 - 785 (1997)
Several γ,δ-unsaturated sulfinyl compounds were prepared and their reactions with p-toluenesulfonic acid were examined. Conformationally rigid γ,δ-unsaturated sulfinyl compounds such as endo-(alkylsulfinyl)norbornene or 1-(alkylsulfinyl)-2-isopropenylbenzene derivatives afforded 1,3-oxathianes through intramolecular Pummerer rearrangement.
