
Chemical and Pharmaceutical Bulletin p. 778 - 785 (1997)
Update date:2022-08-03
Topics:
Abe, Hitoshi
Fujii, Hiroyuki
Masunari, Chieko
Itani, Junko
Kashino, Setsuo
Shibaike, Kentaro
Harayama, Takashi
Several γ,δ-unsaturated sulfinyl compounds were prepared and their reactions with p-toluenesulfonic acid were examined. Conformationally rigid γ,δ-unsaturated sulfinyl compounds such as endo-(alkylsulfinyl)norbornene or 1-(alkylsulfinyl)-2-isopropenylbenzene derivatives afforded 1,3-oxathianes through intramolecular Pummerer rearrangement.
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