191729-46-1Relevant academic research and scientific papers
Studies on the regioselectivity of Horner-Wadsworth-Emmons (HWE) reactions on 3,4-enuloses. Further evidence of phosphonate-phosphate rearrangements through five membered cyclic intermediates
Moradei, Oscar M.,Du Mortier, Cecile M.,Fernandez Cirelli, Alicia
, p. 709 - 719 (2007/10/03)
The Horner-Wadsworth-Emmons (HWE) reaction was performed on methyl 3,6-di-0-benzoyl-2-deoxy-α-D-glycero-hex-2-enopyranosid-4-ulose (1) with the potassium enolates of dimethyl [(methoxycarbonyl)methyl]phosphonate (2) or diethyl [(ethoxycarbonyl) methyl]pho
Anomalous Horner-Wadsworth-Emmons reactions on 3,4-enuloses
Moradei, Oscar M.,Du Mortier, Cecile M.,Cirelli, Alicia Fernandez
, p. 7397 - 7402 (2007/10/03)
Pyranosic enuloses were subjected to Horner-Wadsworth-Emmons (HWE) conditions using the enolate of dimethyl(methoxycarbonyl)methyl phosphonate and its ethyl analogue. 3-O-Phosphorylation of the products as well as an unusual stereospecificity were observe
