191805-01-3

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 191805-00-2 (3aS,4R,6aR)-6a-Hydroxymethyl-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole-4-carboxylic acid methyl ester 
• 191804-99-6 Acetic acid (3aS,6S,6aS)-6-cyano-2,2-dimethyl-dihydro-furo[3,4-d][1,3]dioxol-3a-ylmethyl ester 
• 91738-40-8 (3-C-acetoxymethyl)-1-O-acetyl-2,3-O-isopropylidene-β-D-erythrofuranose 
• 70147-50-1 3-C-hydroxymethyl-2,3-O-isopropylidene-β-D-erythrofuranoside 

Downstream Products

• 191805-03-5 (E)-3-[(3aS,4S,6aS)-6a-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-3-cyano-acrylic acid tert-butyl ester 
• 191805-04-6 3-[(3aS,4S,6aS)-6a-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-pyrrole-2,5-dione 
• 191805-02-4 (3aS,4R,6aS)-6a-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole-4-carboxylic acid 

Relevant academic research and scientific papers

Synthesis of D-Apio-β-D-furanosyl Maleimide, an Analogue of Showdomycin with Transposed Hydroxymethyl Group

Apioshowdomycin (3-(D-apio-β-D-furanosyl)-1H-pyrrole-2,5-dione, 2) has been prepared as an analogue of the C-nucleoside showdomycin (1) in eight steps and with 5% overall yield, starting from 2,3-O-isopropylidene-D-apio-β-D-furanose (3).