191939-01-2Relevant academic research and scientific papers
Synthesis of manoalide using a 1,2-metallate rearrangement
Pommier, Agnes,Kocienski, Philip J.
, p. 1139 - 1140 (1997)
Manoalide, a marine antiinflammatory sesterterpenoid, has been synthesised using a 1,2-metallate rearrangement of a higher order cuprate and a Pd0-catalysed carbonylation of an iodo alkene to generate the central dihydropyranone ring.
