192057-12-8 Usage
Uses
Used in Organic Synthesis:
TsDACH RuCl(p-cyMene) is used as a catalyst for enantioselective reactions in organic synthesis, leveraging its chiral nature to impart selectivity to the reactions, which is crucial for producing enantiomerically pure compounds.
Used in Asymmetric Catalysis:
In the field of asymmetric catalysis, TsDACH RuCl(p-cyMene) is employed as a catalyst to facilitate enantioselective transformations, enabling the production of chiral molecules with a specific three-dimensional arrangement, which is essential in pharmaceuticals and agrochemicals.
Used in Pharmaceutical Industry:
TsDACH RuCl(p-cyMene) is utilized as a catalyst in the synthesis of pharmaceutical compounds, where the chiral properties of the compound are vital for the biological activity and selectivity of the final drug product.
Used in Agrochemical Industry:
Similarly, in agrochemicals, TsDACH RuCl(p-cyMene) is used as a catalyst for the synthesis of chiral pesticides and other agrochemicals, ensuring the desired enantioselectivity for effective and targeted pest control.
Check Digit Verification of cas no
The CAS Registry Mumber 192057-12-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,9,2,0,5 and 7 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 192057-12:
(8*1)+(7*9)+(6*2)+(5*0)+(4*5)+(3*7)+(2*1)+(1*2)=128
128 % 10 = 8
So 192057-12-8 is a valid CAS Registry Number.
192057-12-8Relevant academic research and scientific papers
Asymmetric Hydrogenation of In Situ Generated Isochromenylium Intermediates by Copper/Ruthenium Tandem Catalysis
Miao, Tingting,Tian, Zi-You,He, Yan-Mei,Chen, Fei,Chen, Ya,Yu, Zhi-Xiang,Fan, Qing-Hua
supporting information, p. 4135 - 4139 (2017/04/03)
The first asymmetric hydrogenation of in situ generated isochromenylium derivatives is enabled by tandem catalysis with a binary system consisting of Cu(OTf)2 and a chiral cationic ruthenium–diamine complex. A range of chiral 1H-isochromenes were obtained in high yields with good to excellent enantioselectivity. These chiral 1H-isochromenes could be easily transformed into isochromanes, which represent an important structural motif in natural products and biologically active compounds. The chiral induction was rationalized by density functional theory calculations.
Water-soluble arene ruthenium complexes containing a trans-1,2- diaminocyclohexane ligand as enantioselective transfer hydrogenation catalysts in aqueous solution
Canivet, Jerome,Labat, Gael,Stoeckli-Evans, Helen,Suess-Fink, Georg
, p. 4493 - 4500 (2007/10/03)
The cationic chloro complexes [(arene)Ru(H2N∩NH 2)Cl]+ (1: arene = C6H6; 2: arene = p-MeC6H4iPr; 3: arene = C6Me6) have been synthesised from the correspond
