192126-32-2Relevant academic research and scientific papers
A stannaethene with a planar environment of the tricoordinated tin and carbon atoms
Weidenbruch, Manfred,Kilian, Hartmut,Stuermann, Martin,Pohl, Siegfried,Saak, Wolfgang,Marsmann, Heinrich,Steiner, Dirk,Berndt, Armin
, p. 255 - 257 (1997)
Addition of the diarylstannylene R″2Sn (R″ = 2-tBu-4,5,6-Me3C6H) to the cryptodiborylcarbene (Me3Si)2C(BtBu)2C furnishes the stannaethene (Me3Si)2C(BtBu)2C=SnR″2 (10). The X-ray structure analysis of 10 reveals a strictly planar environment of the tricoordinated tin and carbon atoms and a slight twisting of the Sn=C double bond.
