A stannaethene with a planar environment of the tricoordinated tin and carbon atoms

DOI: 10.1016/S0022-328X(96)06666-1

Source and publish data:

Journal of Organometallic Chemistry p. 255 - 257 (1997)

Update date:2022-07-30

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Authors:

Weidenbruch, Manfred

Kilian, Hartmut

Stuermann, Martin

Pohl, Siegfried

Saak, Wolfgang

Marsmann, Heinrich

Steiner, Dirk

Berndt, Armin

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Article abstract of DOI:10.1016/S0022-328X(96)06666-1

Addition of the diarylstannylene R″₂Sn (R″ = 2-^tBu-4,5,6-Me₃C₆H) to the cryptodiborylcarbene (Me₃Si)₂C(B^tBu)₂C furnishes the stannaethene (Me₃Si)₂C(B^tBu)₂C=SnR″₂ (10). The X-ray structure analysis of 10 reveals a strictly planar environment of the tricoordinated tin and carbon atoms and a slight twisting of the Sn=C double bond.

Full text of DOI:10.1016/S0022-328X(96)06666-1

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