19213-98-0Relevant academic research and scientific papers
Synthesis and Hydrolysis of 4-Substituted 2-Adamantyl p-Nitrobenzenesulfonates
Grob, Cyril A.,Wittwer, Gerhard,Rao, K. Rama
, p. 760 - 769 (2007/10/02)
Several 4e-substituted 2e- and 2a-adamantyl p-nitrobenzenesulfonates have been prepared by new routes.Their hydrolysis products are described.
STEREOSPECIFIC BROMINE REPLACEMENT IN THE SYNTHESIS OF 4(e) AND 4(a)-DEUTERIOADAMANTAN-2-ONES
Chang, Tsung C.,Gadberry, J. Frederic,Lightner, David A.
, p. 1321 - 1332 (2007/10/02)
Stereospecific introduction of deuterium on the adamantane skeleton has been accomplished with LiAlD(OCH3)3-CuI.
SYNTHESIS OF 4a-, 4e-PHENYLADAMANTANONES AND 2,4-o-BENZENOADAMANTANE BY Π-ROUTE
Hoffmann, Guenter Georg,Klein, Harald
, p. 199 - 202 (2007/10/02)
The acid catalysed reaction of 4-oxa-homoadamantan-5-one (1) with benzene yielded a mixture of 4a-phenyladamantan-2-one (7), the equatorial isomer (8) and 2-phenyl-2,4-o-benzenoadamantane (9).A plausible reaction pathway for the occurence of 9
SYNTHESIS, SEPARATION, AND IDENTIFICATION OF 4-BROMOADAMANTAN-2-ONE STEREOISOMERS
Vodicka, Ludek,Triska, Jan,Hajek, Milan
, p. 2670 - 2674 (2007/10/02)
A one-step synthesis of mixture of stereoisomers of 4-bromoadamantan-2-one based on the reaction of adamantan-2-one with hydroxylamine hydrochloride in hydrobromic acid is described.The pure stereoisomers were isolated by elution chromatography on silica gel, and their NMR spectra with the Eu(FOD)3 shift reagent, mass spectra, IR spectra, and dipole moments were measured.
