19213-99-1

Upstream product

• 29844-85-7 tricyclo<4.3.1.0^3,8>dec-4-ene 
• 51020-64-5 4-Hydroxyadamantan-2-on 
• 75-26-3 isopropyl bromide 
• 19214-00-7 2,4-adamantanedione 
• 83177-05-3 4a-tetrahydropyranoxy-2e-toluene-p-sulphonoxyadamantane 
• 26278-43-3 4^a-Hydroxytricyclo<3.3.1.1^3,7>decan-2-on 
• 83176-94-7 4a-(3,5-dinitrobenzoyloxy)adamantan-2e-ol 
• 83177-06-4 4a-tetrahydropyranoxy-adamantan-2e-ol 
• 26278-43-3 4^e-Hydroxytricyclo<3.3.1.1^3,7>decan-2-on 
• 594-19-4 tert.-butyl lithium 

Relevant academic research and scientific papers

Synthesis and reactivity studies of 2,4-(dimethylmethano)-2,4-didehydroadamantane: A comparison with an unsubstituted analogue

We prepared 2,4-(dimethylmethano)-2,4-didehydroadamantane (1), a gem-dimethyl[3.1.1]propellane, and systematically examined its chemical behavior in relation to its unsubstituted analogue 2,4-methano-2,4-didehydroadamantane (2). 2,4-(Dimethylmethano)-2,4-

Syntheses and NMR Spectra of Substituted 2-tert-Butyladamantan-2-ols

The synthesis of a number of substituted 2-tert-butyladamantan-2-ols from the corresponding ketones is described.In addition to these addition reactions, some unexpected rearrangements were observed.Reaction mechanisms are proposed to rationalize the experimental results. 13C NMR spectra of some adamantanes are discussed in terms of substituent interaction effects.