192137-08-9Relevant academic research and scientific papers
Scalable, easy synthesis, and efficient isolation of arylnitromethanes: a revival of the Victor Meyer reaction
Alaime, Thibaud,Delots, Audrey,Pasquinet, Eric,Suzenet, Franck,Guillaumet, Gérald
, p. 1337 - 1341 (2017/01/21)
A modified approach to synthesize and isolate arylnitromethanes is described. The method takes advantage of the significant difference in acidity between the arylnitromethane and the major impurity of the reaction, the nitrite ester. The arylnitromethanes resulting from this process are obtained in high yields and are analytically pure, i.e., they do not require distillation or further purification, which is a comfortable improvement of the ancestral Victor Meyer reaction.
Facile preparation of benzylic iodides under solvent-free conditions using microwave irradiation
Lee, Jong Chan,Park, Jin Young,Yoo, Eun Sang
, p. 2095 - 2099 (2007/10/03)
Benzylic alcohols are rapidly converted to the corresponding benzylic iodides using combination of p-toluenesulfonic acid (PTSA) and potassium iodide under solvent-free microwave irradiation conditions.
Solvent Effects on Proton Transfer Reactions: Benzoate Ion Promoted Deprotonation Reactions of Arylnitromethanes in Methanol Solution
Gandler, Joseph R.,Saunders, Oliver L.,Barbosa, Ronald
, p. 4677 - 4682 (2007/10/03)
Second-order rate constants and equilibrium constants have been determined for the benzoate ion promoted deprotonation reactions of (m-nitrophenyl)nitromethane, (p-nitrophenyl)nitromethane, and (3,5-dinitrophenyl)nitromethane in methanol solution. The pK
