192188-42-4

Basic information

• Product Name: 7-(tert-butyl-dimethyl-silanyloxy)-1-phenyl-hept-2-yn-1-one
• Synonyms: 7-(tert-butyl-dimethyl-silanyloxy)-1-phenyl-hept-2-yn-1-one
• CAS NO: 192188-42-4
• Molecular Weight: 316.516
• Mol File: 192188-42-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 7-(tert-butyl-dimethyl-silanyloxy)-1-phenyl-hept-2-yn-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 7-(tert-butyl-dimethyl-silanyloxy)-1-phenyl-hept-2-yn-1-one(192188-42-4)
• EPA Substance Registry System: 7-(tert-butyl-dimethyl-silanyloxy)-1-phenyl-hept-2-yn-1-one(192188-42-4)

Safety Data

• Hazardous Substances Data: 192188-42-4(Hazardous Substances Data)

Upstream product

• 6919-61-5 N-methoxy-N-methylbenzamide 
• 73448-13-2 tert-butyldimethylsilyl hex-5-yn-1-yl ether 
• 98-88-4 benzoyl chloride 
• 150422-67-6 6-(t-butyldimethylsilyloxy)-1-trimethylsilylhex-1-yne 

Downstream Products

• 740816-32-4 5-[2-Oxo-2-phenyl-eth-(E)-ylidene]-nonanal 

Relevant articles and documents

Enantioselective formation of quaternary stereocenters using the catalytic intramolecular Stetter reaction

Asymmetric formation of quaternary stereocenters has been accomplished using the catalytic intramolecular Stetter reaction. A?variety of tethered aldehydes and Michael acceptors are cyclized in excellent yields and enantioselectivities.

Direct alkynyl group transfer from silicon to copper: New preparation method of alkynylcopper (I) reagents

A first observation of the direct alkynyl group transfer from silicon to copper is reported. The silicon group of alkynylsilanes was smoothly replaced by copper (I) chloride in DMI to give the corresponding copper (I) acetylides. This transformation was a