192226-55-4

Upstream product

• 156492-30-7 4,7-dibromo-1,10-phenanthroline 
• 536-74-3 phenylacetylene 
• 5394-23-0 4,7-dichloro-1,10-phenanthroline 
• 1414364-63-8 C₃₀H₂₀N₂ 
• 3922-40-5 1,10-phenanthroline-4,7-diol 

Downstream Products

• 192226-52-1 C₆H₅CCC₁₂N₂H₆CCC₆H₅CuC₆H₅C₆H₄C₁₂N₂H₆C₆H₄C₆H₅⁽¹⁺⁾ 
• 192226-37-2 (C₆H₅C₆H₄C₁₂N₂H₆C₆H₄C₆H₅)2Cu⁽¹⁺⁾*BF₄^(1-)=(C₆H₅C₆H₄C₁₂N₂H₆C₆H₄C₆H₅)2CuBF₄ 
• 262610-79-7 [AgC₁₂H₆N₂(C₆H₃(CH₃O)2)2(C₁₂H₆N₂(C₂C₆H₅)2)]⁽¹⁺⁾*BF₄^(1-)=[AgC₁₂H₆N₂(C₆H₃(CH₃O)2)2C₁₂H₆N₂(C₂C₆H₅)2]BF₄ 
• 192226-43-0 (CH₃O)2C₆H₃C₁₂N₂H₆C₆H₃(OCH₃)2CuC₆H₅CCC₁₂N₂H₆CCC₆H₅⁽¹⁺⁾*BF₄^(1-)=(CH₃O)2C₆H₃C₁₂N₂H₆C₆H₃(OCH₃)2CuC₁₂N₂H₆(CCC₆H₅)2BF₄ 
• 192226-45-2 (CH₃)3C₆H₂C₁₂N₂H₆C₆H₂(CH₃)3CuC₆H₅CCC₁₂N₂H₆CCC₆H₅⁽¹⁺⁾*BF₄^(1-)=(CH₃)3C₆H₂C₁₂N₂H₆C₆H₂(CH₃)3CuC₁₂N₂H₆(CCC₆H₅)2BF₄ 
• 1415558-79-0 C₆₄H₄₆CuN₂P₂⁽¹⁺⁾*BF₄^(1-) 
• 192226-39-4 (C₆H₅CCC₁₂N₂H₆CCC₆H₅)2Cu⁽¹⁺⁾*BF₄^(1-)=(C₆H₅CCC₁₂N₂H₆CCC₆H₅)2CuBF₄ 
• 192226-41-8 (CH₃)2C₆H₃C₁₂N₂H₆C₆H₃(CH₃)2CuC₆H₅CCC₁₂N₂H₆CCC₆H₅⁽¹⁺⁾*BF₄^(1-)=(CH₃)2C₆H₃C₁₂N₂H₆C₆H₃(CH₃)2CuC₁₂N₂H₆(CCC₆H₅)2BF₄ 

Relevant academic research and scientific papers

Synthesis, crystal structure, and conjugation properties of phenanthroline copper phosphine complexes

Facial synthetic method of 4,7-position conjugation extended phenanthrolines and X-ray structure of copper phosphine phenanthroline complexe were reported. The crystal structures showed π-stacking and hydrogen bonding, and a small torsional angle between phen and phenylacetylene. These complexes exhibited strong conjugation dependant MLCT luminescence. The electronic and fluorescence spectra displayed a gradual red shift of the MLCT band as the conjugation increased. The presence of the phenyl groups reduced the energy of the π∞ state in the d-π∞ MLCT transition, allowing for the red shift. The electron-donating tri-isopropylsilyl (TIPS) groups on the ethynyl moiety increased the energy of the MLCT charge vector, allowing for the blue shift at the luminescence.

Synthesis of 4,7-Disubstituted Phenanthrolines as Key Building Blocks for the First Preparation of Macrocyclic Mono- and Bisphenanthrolines with exo-Coordination Sites

The preparation of various 4,7-bisalkynylated phenanthrolines and 4,7-bis(4-hydroxyphenoxy)phenanthroline as well as their use in the synthesis of the first macrocyclic phenanthrolines and bisphenanthrolines with exo-coordination sites is described.