192319-08-7

Basic information

• Product Name: Ru(C₅H₅)(P(C₆H₅)3)(C₆H₅C₁₅H₁₀N₃)⁽¹⁺⁾*PF₆^(1-)=[Ru(C₅H₅)(P(C₆H₅)3)(C₆H₅C₁₅H₁₀N₃)]PF₆
• CAS NO: 192319-08-7
• Molecular Weight: 882.79
• Mol File: 192319-08-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ru(C₅H₅)(P(C₆H₅)3)(C₆H₅C₁₅H₁₀N₃)⁽¹⁺⁾*PF₆^(1-)=[Ru(C₅H₅)(P(C₆H₅)3)(C₆H₅C₁₅H₁₀N₃)]PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: Ru(C₅H₅)(P(C₆H₅)3)(C₆H₅C₁₅H₁₀N₃)⁽¹⁺⁾*PF₆^(1-)=[Ru(C₅H₅)(P(C₆H₅)3)(C₆H₅C₁₅H₁₀N₃)]PF₆(192319-08-7)
• EPA Substance Registry System: Ru(C₅H₅)(P(C₆H₅)3)(C₆H₅C₁₅H₁₀N₃)⁽¹⁺⁾*PF₆^(1-)=[Ru(C₅H₅)(P(C₆H₅)3)(C₆H₅C₁₅H₁₀N₃)]PF₆(192319-08-7)

Safety Data

• Hazardous Substances Data: 192319-08-7(Hazardous Substances Data)

Upstream product

• 32993-05-8 chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) 
• 58345-97-4 4'-phenyl-2,2':6',2-terpyridine 

Relevant articles and documents

Synthesis and molecular structure of [CpRu(PPh3)(Phterpy-N,N′)]Cl complex: Hdentate nature of Phterpy and diterpy

Ligand displacement reactions of the complex [CpRu(PPh3)2Cl] were investigated with N3 terdentate ligands, 4′-phenyl-2,2′: 6,2″-terpyridine (Phterpy) and 1,4-bis(2,2′: 6′,2″-terpyridin-4-yl)benzene (diterpy). The [CpRu(PPh3)2Cl] reacted with these ligands to form stable complexes of the type [CpRu(PPh3)(Phterpy)]X (X = Cl-, PF-6) and [{CpRu(PPh3)}(diterpy){Ru(PPh3)Cp}]X2 (X = CL- PF-6) where the respective ligands coordinate in a bidentate fashion. The X-ray crystal structure of the former complex was determined showing octahedral geometry about the metal center assuming the cyclopentadienyl ligand occupying three coordination sites and Phterpy acts as a bidentate ligand.