192504-25-9

Upstream product

• 192504-24-8 Acetic acid (E)-(2S,4R,5R)-10-(tert-butyl-diphenyl-silanyloxy)-5-hydroxy-2-methyl-4-(tetrahydro-pyran-2-yloxy)-dec-6-enyl ester 
• 192504-23-7 Acetic acid (E)-(2S,4R,5S)-10-(tert-butyl-diphenyl-silanyloxy)-5-hydroxy-2-methyl-4-(tetrahydro-pyran-2-yloxy)-dec-6-enyl ester 
• 192504-20-4 Acetic acid (2S,4R)-4,5-dihydroxy-2-methyl-pentyl ester 
• 192504-22-6 tert-butyl{[(4E)-5-iodopent-4-en-1-yl]oxy}diphenylsilane 
• 1026700-47-9 Acetic acid (2S,4R)-2-methyl-5-oxo-4-(tetrahydro-pyran-2-yloxy)-pentyl ester 
• 192504-21-5 Acetic acid (2S,4R)-5-hydroxy-2-methyl-4-(tetrahydro-pyran-2-yloxy)-pentyl ester 
• 17155-25-8 Acetic acid (S)-2-methyl-pent-4-enyl ester 
• 175272-36-3 (4R)-4-Benzyl-3-[(2S)-2-methyl-4-pentenoyl]-1,3-oxazolidin-2-one 
• 127793-62-8 4-((tert-butyldiphenylsilyl)oxy)butanal 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 5673-98-3 (S)-(-)-2-methyl-4-penten-1-ol 
• 110-87-2 3,4-dihydro-2H-pyran 

Downstream Products

• 192504-26-0 (E)-(3R,5R,6S)-11-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-5-(tetrahydro-pyran-2-yloxy)-6-triisopropylsilanyloxy-undec-7-enenitrile 
• 192504-27-1 2-[(E)-(1R,2S)-7-(tert-Butyl-diphenyl-silanyloxy)-1-((R)-2-methyl-pent-4-ynyl)-2-triisopropylsilanyloxy-hept-3-enyloxy]-tetrahydro-pyran 
• 1026062-63-4 Acetic acid (1S,2R,4R)-1-[(E)-5-(tert-butyl-diphenyl-silanyloxy)-pent-1-enyl]-4-methyl-2-(tetrahydro-pyran-2-yloxy)-hept-6-ynyl ester 

Relevant academic research and scientific papers

Synthetic studies toward potent cytotoxic agent amphidinolide B: Synthesis of the entire Cl-C13 moiety of the bottom half

Sharpless asymmetric dihydroxylation and Nozaki-Hiyama-Kishi's Cr(II)-mediated coupling between an α-alkoxyaldehyde and a vinyl iodide are the key steps in the stereoselective synthesis of the entire C1-C13 segment of the bottom-half of amphidinolide B.