192574-05-3

Basic information

• Product Name: (-)-7-(2-nitrophenyl)-2-vinylidene-4-azatricyclo[5.2.2.0^4,8]undecan-11-one
• Synonyms: (-)-7-(2-nitrophenyl)-2-vinylidene-4-azatricyclo[5.2.2.0^4,8]undecan-11-one
• CAS NO: 192574-05-3
• Molecular Weight: 310.353
• Mol File: 192574-05-3.mol

Chemical Properties

• CAS DataBase Reference: (-)-7-(2-nitrophenyl)-2-vinylidene-4-azatricyclo[5.2.2.0^4,8]undecan-11-one(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-7-(2-nitrophenyl)-2-vinylidene-4-azatricyclo[5.2.2.0^4,8]undecan-11-one(192574-05-3)
• EPA Substance Registry System: (-)-7-(2-nitrophenyl)-2-vinylidene-4-azatricyclo[5.2.2.0^4,8]undecan-11-one(192574-05-3)

Safety Data

• Hazardous Substances Data: 192574-05-3(Hazardous Substances Data)

Upstream product

• 222162-04-1 (3aR,7aS)-3a-(2-Nitro-phenyl)-4-oxo-5-phenylselanyl-octahydro-indole-1-carboxylic acid 1-chloro-ethyl ester 
• 138040-07-0 2-Allyl-2-(2-nitrophenyl)-1,3-cyclohexanedione 
• 192431-40-6 (3aR,7aS)-3a-(2-Nitro-phenyl)-1-(4-trimethylsilanyl-but-2-ynyl)-1,2,3,3a,7,7a-hexahydro-indol-4-one 
• 192431-42-8 (3aR,7aS)-3a-(2-Nitro-phenyl)-4-oxo-octahydro-indole-1-carboxylic acid 1-chloro-ethyl ester 
• 222162-00-7 (3aR,7aS)-3a-(2-Nitro-phenyl)-4-oxo-2,3,3a,4,7,7a-hexahydro-indole-1-carboxylic acid 1-chloro-ethyl ester 
• 192431-33-7 (3aR,7aS)-N-[(S)-α-Methylbenzyl]-3a-(2-nitrophenyl)octahydroindol-4-one 

Downstream Products

• 6883-33-6 (-)-tubifolidine 

Relevant articles and documents

A general synthetic entry to Strychnos alkaloids of the curan type via a common 3a-(2-nitrophenyl)hexahydroindol-4-one intermediate. Total syntheses of (±)- and (-)-tubifolidine, (±)-akuammicine, (±)-19,20-dihydroakuammicine, (±)-norfluorocurarine, (±)-ec

A general strategy for the synthesis of pentacyclic Strychnos alkaloids with the curan skeleton has been developed. It utilizes 3a-(2-nitrophenyl)hexahydroindol-4-one (23), which was prepared from 2-allyl-2-(2-nitrophenyl)-1,3-cyclohexanedione (15), as th