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1927-68-0

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1927-68-0 Usage

General Description

2-Butoxyoxane, also known as butyl oxirane, is a chemical compound with the molecular formula C8H16O2. It is commonly used as a solvent in various industrial and commercial applications, including in the production of paints, coatings, and cleaning products. It is a clear, colorless liquid with a mild, ether-like odor, and it is flammable and volatile. 2-Butoxyoxane is known to have acute toxic effects when inhaled, ingested, or in contact with the skin, and prolonged exposure can cause irritation to the respiratory system and other adverse health effects. Therefore, proper handling, storage, and use of 2-butoxyoxane is important to ensure safety for workers and the environment.

Check Digit Verification of cas no

The CAS Registry Mumber 1927-68-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,9,2 and 7 respectively; the second part has 2 digits, 6 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1927-68:
(6*1)+(5*9)+(4*2)+(3*7)+(2*6)+(1*8)=100
100 % 10 = 0
So 1927-68-0 is a valid CAS Registry Number.
InChI:InChI=1/C9H18O2/c1-2-3-7-10-9-6-4-5-8-11-9/h9H,2-8H2,1H3

1927-68-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-butoxyoxane

1.2 Other means of identification

Product number -
Other names 2-Butoxytetrahydropyran

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1927-68-0 SDS

1927-68-0Relevant articles and documents

Crystal structure, thermal decomposition mechanism and catalytic performance of hexaaquaaluminum methanesulfonate

Wang, Rui,Li, Rongrong,Jiang, Heng,Gong, Hong,Bi, Yanfeng

, p. 1327 - 1338 (2017/04/06)

Hexaaquaaluminum methanesulfonate crystals, [Al(H2O)6][CH3SO3]3 were synthesized by a hydrothermal reaction of Al(OH)3 with methanesulfonic acid. Single-crystal diffraction determination revealed that Al3+ was coordinated by six water molecules in octahedral geometry, while the CH3SO3 – anion connected with Al3+ through coordinated water molecules by hydrogen bonds. The six-coordinate environment of Al was also determined by 27Al MAS NMR measurement. Thermogravimetric analysis and Fourier transform infrared spectroscopy showed that the decomposition intermediate at 265–365?°C was Al2(μ-OH)(CH3SO3)5 and the final product was amorphous Al2O3 residue with about 0.8 wt% SO3 at 520–800?°C. A pure phase of [Al(H2O)6][CH3SO3]3 was confirmed by powder X-ray diffraction analysis. Esterification of n-butyric acid with n-butanol and ketalization of cyclohexanone with glycol catalyzed by [Al(H2O)6][CH3SO3]3 and Al2(μ-OH)(CH3SO3)5, respectively, proceeded in 100% yield by continuously removing the produced water. In the case of tetrahydropyranylation of n-butanol at room temperature in dichloromethane, the catalytic activity of [Al(H2O)6][CH3SO3]3 was much lower than that of Al2(μ-OH)(CH3SO3)5. Furthermore, both [Al(H2O)6][CH3SO3]3 precursor and Al2(μ-OH)(CH3SO3)5 catalysts could be recycled.

3,5-Dinitrobenzoic acid catalyzed synthesis of 2,3-unsaturated O- and S-glycosides and tetrahydropyranylation of alcohols and phenols

Bodipati, Naganjaneyulu,Palla, Srinivasa Rao,Komera, Venkateshwarlu,Peddinti, Rama Krishna

supporting information, p. 6878 - 6881 (2015/02/02)

A simple procedure for the synthesis of 2,3-unsaturated glycosides in acetonitrile and tetrahydropyranylation of alcohols and phenols in dichloromethane in the presence of 3,5-dinitrobenzoic acid is described. A variety of alcohols and thiols are reacted with glycals to give the desired products in high yields with high α-selectivity.

Solvent-free tetrahydropyranylation of alcohols catalyzed by amine methanesulfonates

Wang, Rui,Sun, Mingzhu,Jiang, Heng

experimental part, p. 61 - 67 (2012/02/16)

A comparative study of tetrahydropyranylation of alcohols under various solvents or solvent-free conditions using different amine methanesulfonates as catalysts shows that tetrahydropyranyl ethers of alcohols are obtained under solvent-free conditions in good yields using catalytic amounts of triethylenediamine methanesulfonate, 1,6-hexanediamine methanesulfonate, diethylenetriamine methanesulfonate and pyridine methanesulfonate, respectively. The reaction occurs readily in short times at room temperature catalyzed by these catalysts, especially triethylenediamine methanesulfonate. Some of the major advantages of this procedure are that the catalysts are environmentally friendly, highly effective, and easy to prepare and handle. The reaction is also clean and needs no solvent, and the work-up is very simple.

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