192711-31-2

Upstream product

• 98-86-2 acetophenone 
• 2459-07-6 methyl pyridine-2-carboxylate 
• 111-83-1 1-bromo-octane 
• 15395-62-7 2-(3-phenyl-1H-pyrazol-5-yl) pyridine 
• 629-27-6 1-Iodooctane 

Downstream Products

• 876061-92-6 cis-[PdCl₂(2-(1-octyl-5-phenyl-1H-pyrazol-3-yl)pyridine)] 
• 876061-94-8 cis-[PtCl₂(2-(1-octyl-5-phenyl-1H-pyrazol-3-yl)pyridine)] 
• 944162-96-3 (η3-allyl)(2-(1-octyl-5-phenyl-1H-pyrazol-3-yl)pyridine)palladium(II) tetrafluoroborate 

Relevant academic research and scientific papers

Molybdenum-catalyzed olefin epoxidation: Ligand effects

We synthesized substituted pyrazolylpyridine ligands to examine their donor properties by spectroscopic (IR, NMR) and computational (AM 1) methods. The influence of the substitution patterns on spectroscopic and thermodynamic features of molybdenum oxobis

Regioselective formation of N-alkyl-3,5-pyrazole derived ligands. A synthetic and computational study

New N-alkyl-3,5-pyrazole derived ligands were synthesized by reaction between 3,5-pyrazole derived ligands and the appropriate haloalkane in toluene or THF using NaOEt or NaH as base. When the precursor ligand bears a pyridyl substituent the alkylation reaction presents a large regioselectivity. Theoretical calculations have been carried out to rationalize the experimental observations. It has been shown that regioselectivity is governed by the formation of Na+-pyrazolide chelate complexes.