19275-14-0Relevant academic research and scientific papers
Continuous Visible-Light Photoflow Approach for a Manganese-Catalyzed (Het)Arene C?H Arylation
Liang, Yu-Feng,Steinbock, Ralf,Yang, Long,Ackermann, Lutz
, p. 10625 - 10629 (2018)
Manganese photocatalysts enabled versatile room-temperature C?H arylation reactions by means of continuous visible-light photoflow, thus allowing for efficient C?H arylations in 30 minutes with ample scope. The robustness of the manganese-catalyzed photoflow strategy was shown by visible light-induced gram-scale synthesis, clearly outperforming the batch performance.
N-Iodosuccinimide and dioxygen in an air-enabled synthesis of 10-phenanthrenols under sunlight
Chen, Bin,Guo, Jia-Dong,Tung, Chen-Ho,Wu, Li-Zhu,Yang, Xiu-Long
supporting information, p. 7193 - 7198 (2021/09/28)
Using a catalytic amount ofN-iodosuccinimide (NIS) in combination with O2in air, an aerobic oxidative reaction was carried out to efficiently and scalably construct a series of 10-phenanthrenols under sunlight at room temperature. Mechanistic studies reveal that H2O2generatedin situwas responsible for the conversion of I2to IOH as a potential initiator for later catalytic cycle.
Interplay of ortho-with spiro-cyclisation during iminyl radical closures onto arenes and heteroarenes
McBurney, Roy T.,Walton, John C.
supporting information, p. 1083 - 1092 (2013/07/19)
Sensitised photolyses of ethoxycarbonyl oximes of aromatic and heteroaromatic ketones yielded iminyl radicals, which were characterised by EPR spectroscopy. Iminyls with suitably placed arene or heteroarene acceptors underwent cyclisations yielding phenan
