192751-13-6

Basic information

• Product Name: Benzoic acid 1-methoxy-4-methyl-1-oxo-2,3-dihydro-1H-1λ⁵-phosphol-3-yl ester
• Synonyms: Benzoic acid 1-methoxy-4-methyl-1-oxo-2,3-dihydro-1H-1λ⁵-phosphol-3-yl ester
• CAS NO: 192751-13-6
• Molecular Weight: 266.233
• Mol File: 192751-13-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid 1-methoxy-4-methyl-1-oxo-2,3-dihydro-1H-1λ⁵-phosphol-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid 1-methoxy-4-methyl-1-oxo-2,3-dihydro-1H-1λ⁵-phosphol-3-yl ester(192751-13-6)
• EPA Substance Registry System: Benzoic acid 1-methoxy-4-methyl-1-oxo-2,3-dihydro-1H-1λ⁵-phosphol-3-yl ester(192751-13-6)

Safety Data

• Hazardous Substances Data: 192751-13-6(Hazardous Substances Data)

Upstream product

• 695-60-3 1-methoxy-3-methyl-2-phospholene 1-oxide 
• 532-32-1 sodium benzoate 
• 192751-09-0 3-Bromo-1-methoxy-4-methyl-2,3-dihydro-phosphole 1-oxide 

Downstream Products

• 192751-18-1 Benzoic acid 4,5-dihydroxy-1-methoxy-4-methyl-1-oxo-1λ⁵-phospholan-3-yl ester 

Relevant articles and documents

Novel synthesis and structure of phosphanyl sugar derivatives

Some phosphanyl sugar derivatives, which are analogs of sugars having a phosphorus atom in place of the ring oxygen, were synthesized from 2-and 3-phospholenes as starting materials. Catalytic cis-dihydroxylation of 2-phospholene or 3-phospholene 1-oxide derivatives with osmium(VIII) oxide in the presence of a cooxidant afforded 3-deoxy-or 1-deoxy-tetrofuranose-type phosphanyl sugar derivatives, respectively. cis-Dihydroxylation of 4-acyloxy-2-phospholene 1-oxide derivatives gave tetrofuranose type phosphanyl sugar derivatives. Some of these derivatives of phosphanyl sugars were subjected to structural analyses using 1H NMR and X-ray crystallography.