192824-20-7Relevant academic research and scientific papers
Synthesis and applications to asymmetric catalysis of a series of mono- and bis(diazaphospholidine) ligands
Smyth,Tye,Eldred,Alcocka,Wills
, p. 2840 - 2849 (2007/10/03)
The synthesis of a series of closely related mono- and bis(diazaphospholidine) ligands has been achieved using the condensation of a diamine with a bis(dimethylamino)arylphosphine. The resulting ligands have given excellent results in palladium-catalysed allylic substitution reactions to form C-C bonds (up to 89% ee) and C-N bonds (up to 78% ee).
Synthesis and applications of a new class of phosphorus donor ligands for asymmetric catalysis
Tye, Heather,Smyth, Donald,Eldred, Colin,Wills, Martin
, p. 1053 - 1054 (2007/10/03)
The synthesis and applications to allylic substitutions of a range of novel ligands based on diazaphospholidines is described; enantiomeric excesses of up to 89% were achieved in an allylic substitution reaction.
