19298-29-4

Usage

InChI:InChI=1/C14H9NO2/c16-14-12-9-5-4-8-11(12)13(15-17-14)10-6-2-1-3-7-10/h1-9H

Upstream product

• 85-52-9 2-Benzoylbenzoic acid 
• 2618-87-3 2-(hydroxyimino-phenyl-methyl)-benzoic acid 
• 54090-90-3 N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide 
• 611-73-4 Benzoylformic acid 
• 574-66-3 Benzophenone oxime 
• 201230-82-2 carbon monoxide 
• 59479-63-9 o--benzophenonoxim 

Downstream Products

• 68371-08-4 2-(α-hydroxy-benzhydryl)-benzophenone oxime 
• 520-03-6 N-phenylphthalimide 
• 62-53-3 aniline 
• 88-99-3 benzene-1,2-dicarboxylic acid 
• 1374301-99-1 4-phenyl-1H-2,3-benzothiazine-1-thione 
• 1374302-03-0 tetraethyl 1-phenyl-4-thioxo-3,4-dihydroisoquinoline-3,3-diyldiphosphonate 
• 135412-34-9 3-Methoxy-1-(4-nitrophenyl)-1H-isoindolium-trifluormethansulfonat 
• 83889-41-2 3-Methoxy-1-phenyl-1H-isoindolium-trifluoromethansulfonat 
• 25365-87-1 3-ethoxy-1-phenyl-1H-isoindole 
• 25365-84-8 3-methoxy-1-phenyl-1H-isoindole 
• 19734-06-6 1,1,4-triphenyl-1H-benzo[d][1,2]oxazine 

Relevant academic research and scientific papers

Palladium-catalyzed Csp2-H carbonylation of aromatic oximes: Selective access to benzo[d][1,2]oxazin-1-ones and 3-methyleneisoindolin-1-ones

A highly selective palladium-catalyzed carbonylation of Csp2-H bonds with aromatic oximes for the synthesis of benzo[d][1,2]oxazin-1-ones and 3-methyleneisoindolin-1-ones has been developed. Interestingly, we found that the N-OH group of the oximes could be used as a directing group and/or an internal oxidant under different conditions. This transformation is supposed to proceed through a hydroxyl-directed ortho-Csp2-H carbonylation or activation of vinyl Csp2-H bond/ortho-Csp2-H carbonylation process. The uses of readily available starting materials, atmospheric pressure of carbon monoxide, as well as operational simplicity make this practical and atom-economical method particularly attractive. This journal is

Palladium-Catalyzed Decarboxylative ortho-C(sp2)?H Aroylation of N-Sulfoximine Benzamides at Room Temperature

A palladium-catalyzed method for the decarboxylative ortho C?H acylation of N-sulfoximine benzamides is developed at room temperature. The catalytic method enables easy access to various functionalized 2-aroylaromatic carboxylic acid derivatives in good isolated yields. Based on our mechanistic studies, a Pd(II)/Pd(IV) catalytic cycle that involves aroyl radical intermediate is proposed for the reaction.

[4,5]-Fused-1,3-disubstituted-1,2-diazine-6-one derivatives with nitrogen containing substitutents in position one for the treatment of neoplasia

[4,5]-Fused-1,3-disubstituted-1,2-diazine-6-one derivatives with nitrogen-containing substituents in position one are useful for inducing or promoting apoptosis and for arresting uncontrolled neoplastic cell proliferation, and are specifically useful in t

Copper-catalysed rearrangement of 4-substituted-2,3-1H-benzoxazine-1-thiones

4-Substituted-2,3-1H-benzoxazine-1-thiones were prepared by the treatment of the corresponding benzoxazine-1-ones with P2S5. The thermal rearrangement of 4-substituted-2,3-1H-benzoxazine-1-thiones, catalysed by metallic copper, yield

Synthesis of Some 4-Substituted 1H-2,3-Benzoxazin-1-ones

The title compounds have been prepared by treating the corresponding o-aroylbenzoic acids with hydroxylamine hydrochloride and sodium acetate in ethanol, and their structures established by elemental analyses and spectral data.The mechanism suggested for