19319-86-9

Basic information

• Product Name: DIBROMO(1,10-PHENANTHROLINE)COPPER(II)
• Synonyms: DIBROMO(1,10-PHENANTHROLINE)COPPER(II)
• CAS NO: 19319-86-9
• Molecular Formula: C12H8Br2CuN2
• Molecular Weight: 403.56
• Product Categories: Catalysis and Inorganic Chemistry;Chemical Synthesis;Copper
• Mol File: 19319-86-9.mol
• Article Data: 2

Chemical Properties

• Melting Point: 280 °C (dec.)(lit.)
• Boiling Point: 365.1°C at 760 mmHg
• Flash Point: 164.8°C
• Appearance: /
• Vapor Pressure: 3.38E-05mmHg at 25°C
• CAS DataBase Reference: DIBROMO(1,10-PHENANTHROLINE)COPPER(II)(CAS DataBase Reference)
• NIST Chemistry Reference: DIBROMO(1,10-PHENANTHROLINE)COPPER(II)(19319-86-9)
• EPA Substance Registry System: DIBROMO(1,10-PHENANTHROLINE)COPPER(II)(19319-86-9)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 19319-86-9(Hazardous Substances Data)

Usage

General Description

Dibromo(1,10-phenanthroline)copper(II) is a coordination compound that consists of a copper (II) ion bonded to two molecules of 1,10-phenanthroline, each containing two bromine atoms. DIBROMO(1,10-PHENANTHROLINE)COPPER(II) is often used as a catalyst in organic synthesis and as a reagent in analytical chemistry. It is known for its ability to catalyze a variety of reactions, including oxidation and reduction processes, and is particularly useful in the synthesis of organic complexes. Dibromo(1,10-phenanthroline)copper(II) has also been studied for its potential applications in materials science, particularly in the development of new electroactive compounds and materials.

InChI:InChI=1/C12H8N2.2BrH.Cu/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;/q;;;+2/p-2/rC12H8N2.Br2Cu/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;1-3-2/h1-8H;

Upstream product

• 66-71-7 1,10-Phenanthroline 
• 7789-45-9 copper(ll) bromide 
• 5144-89-8 1,10-phenanthroline hydrate 

Relevant articles and documents

Design, XRD/HSA-interactions, spectral, thermal, Solvatochromism and DNA-binding of two [Cu(phen)(triene)]Br2 complexes: Experimental and DFT/TD-DFT investigations

Two dicationicCu(II) complexes of [Cu(phen)(NNN)]Br2 (1-2) general formula [phen = 1,10-phenanthroline, NNN = diethelenetriamine (dien) (1) and dipropylenetriamine (dipn)(2)], have been synthesized in very good yields. The two complexes were characterizedvia UV-vis., CHN-EA, MS, FT-IR, thermal, and X-ray crystallographic techniques. XRD data for 1 showed a distorted square pyramidal Cu(II) ions geometry center with three uncoordinated water molecules. TGA were performed to evaluate the interactions strength and found to support the XRD molecular interactions results. The time-dependent density functional theory (TD-DFT) and electron transfer processes were modeled, and consequently the absorption maxima around 610 and 280 nm were attributed to d–d and Phen(π)→Phen(π?) transitions. Positive Gutmann'ssolvatochromismbehavior of both complexes have been recorded. Furthermore, the ability of the two complexes for DNA binding was evaluatedvia absorption studies in the visible region showing high Kb constant values.