19319-86-9

Usage

Uses

Used in Organic Synthesis:
Dibromo(1,10-phenanthroline)copper(II) is used as a catalyst for various organic reactions, including oxidation and reduction processes. Its catalytic properties enable efficient and selective transformations in the synthesis of organic complexes.
Used in Analytical Chemistry:
Dibromo(1,10-phenanthroline)copper(II) is used as a reagent in analytical chemistry, where its unique properties can be utilized for the detection, quantification, or analysis of specific compounds or elements.
Used in Materials Science:
Dibromo(1,10-phenanthroline)copper(II) is studied for its potential applications in the development of new electroactive compounds and materials. Its coordination chemistry and catalytic properties make it a promising candidate for creating innovative materials with enhanced properties for various applications.

InChI:InChI=1/C12H8N2.2BrH.Cu/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;/q;;;+2/p-2/rC12H8N2.Br2Cu/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;1-3-2/h1-8H;

Upstream product

• 66-71-7 1,10-Phenanthroline 
• 7789-45-9 copper(ll) bromide 
• 5144-89-8 1,10-phenanthroline hydrate 

Relevant academic research and scientific papers

Design, XRD/HSA-interactions, spectral, thermal, Solvatochromism and DNA-binding of two [Cu(phen)(triene)]Br2 complexes: Experimental and DFT/TD-DFT investigations

Two dicationicCu(II) complexes of [Cu(phen)(NNN)]Br2 (1-2) general formula [phen = 1,10-phenanthroline, NNN = diethelenetriamine (dien) (1) and dipropylenetriamine (dipn)(2)], have been synthesized in very good yields. The two complexes were characterizedvia UV-vis., CHN-EA, MS, FT-IR, thermal, and X-ray crystallographic techniques. XRD data for 1 showed a distorted square pyramidal Cu(II) ions geometry center with three uncoordinated water molecules. TGA were performed to evaluate the interactions strength and found to support the XRD molecular interactions results. The time-dependent density functional theory (TD-DFT) and electron transfer processes were modeled, and consequently the absorption maxima around 610 and 280 nm were attributed to d–d and Phen(π)→Phen(π?) transitions. Positive Gutmann'ssolvatochromismbehavior of both complexes have been recorded. Furthermore, the ability of the two complexes for DNA binding was evaluatedvia absorption studies in the visible region showing high Kb constant values.

Syntheses, characterization and optical properties of some copper(I) halides with 1,10-phenanthroline ligand

The hydrothermal reactions of CuX2 or CuX with phen (1,10-phenanthroline) have resulted in the syntheses of eight compounds 1-8. In these, 1:1 adducts of CuX/phen are reported: ionic [Cu(PhBn)2] [CuX2] (X = Cl 1, Br 2) and dimer [Cu2I2(phen)] 3; the trinuclear clusters [Cu3X3(phen)2] (X = Br 5, I 7) were first prepared and the structures can be best described as 1:1 adducts of dimers and CuX; the chain compounds 6 and 8 belong to the same series with the formula [CuX2L] (L = organic ligand), but the chain arrangement is different; the structure of 4 is yet being refined. Compounds 1-8 have a high thermal stability. The third-order nonlinear optical properties of compounds 5, 6 and 8 were investigated and all exhibit a reverse saturable absorption (α2 > 0) and self-defocusing performance (n 2 0).