193224-47-4Relevant academic research and scientific papers
Synthesis and intramolecular photocycloadditions of 2-acyloxy-3-hexenoyl cyclohexenones: Diastereoselectivity in the intramolecular [2+2] photocycloadditions of alkenes and cyclohexenones tethered by four atoms
Crimmins, Michael T.,King, Bryan W.,Watson, Paul S.,Guise, Lisa E.
, p. 8963 - 8974 (1997)
The intramolecular [2+2] photocycloaddition of 2-acyloxy-2-3- hexenoylcyclohexenones has been shown to be highly diastereoselective. The cycloadditions produce exclusively cis fused products and the sense and level of selectivity is consistent with a molecular mechanics model for initial bond formation in the stepwise cycloaddition.
