Tetrahedron p. 8963 - 8974 (1997)
Update date:2022-08-03
Topics:
Crimmins, Michael T.
King, Bryan W.
Watson, Paul S.
Guise, Lisa E.
The intramolecular [2+2] photocycloaddition of 2-acyloxy-2-3- hexenoylcyclohexenones has been shown to be highly diastereoselective. The cycloadditions produce exclusively cis fused products and the sense and level of selectivity is consistent with a molecular mechanics model for initial bond formation in the stepwise cycloaddition.
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