193686-17-8

Basic information

• Product Name: (6S,3Z)-1-acetyl-4-(4-methoxybenzyl)-6-methyl-3-(2,4,5-trimethoxy-3-methylbenzylidene)piperazine-2,5-dione
• Synonyms: (6S,3Z)-1-acetyl-4-(4-methoxybenzyl)-6-methyl-3-(2,4,5-trimethoxy-3-methylbenzylidene)piperazine-2,5-dione
• CAS NO: 193686-17-8
• Molecular Weight: 482.533
• Mol File: 193686-17-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (6S,3Z)-1-acetyl-4-(4-methoxybenzyl)-6-methyl-3-(2,4,5-trimethoxy-3-methylbenzylidene)piperazine-2,5-dione(CAS DataBase Reference)
• NIST Chemistry Reference: (6S,3Z)-1-acetyl-4-(4-methoxybenzyl)-6-methyl-3-(2,4,5-trimethoxy-3-methylbenzylidene)piperazine-2,5-dione(193686-17-8)
• EPA Substance Registry System: (6S,3Z)-1-acetyl-4-(4-methoxybenzyl)-6-methyl-3-(2,4,5-trimethoxy-3-methylbenzylidene)piperazine-2,5-dione(193686-17-8)

Safety Data

• Hazardous Substances Data: 193686-17-8(Hazardous Substances Data)

Upstream product

• 2503-32-4 ethyl N-(benzyloxycarbonyl)-L-alanylglycinate 
• 4526-77-6 (S)-3-methyl-2,5-piperazinedione 
• 66959-35-1 ethyl L-alanylglycinate 
• 74124-56-4 (3S)-1,4-diacetyl-3-methylpiperazine-2,5-dione 
• 824-94-2 p-methoxybenzyl chloride 
• 193686-16-7 (6S,3Z)-1-acetyl-6-methyl-3-(2,4,5-trimethoxy-3-methylbenzylidene)piperazine-2,5-dione 
• 60059-09-8 2,4,5-trimethoxy-3-methylbenzaldehyde 

Downstream Products

• 193686-36-1 (6S,3Z)-4-(4-methoxybenzyl)-1,6-dimethyl-3-(2,4,5-trimethoxy-3-methylbenzylidene)piperazine-2,5-dione 
• 193686-18-9 (6S,3Z)-4-(4-methoxybenzyl)-6-methyl-3-(2,4,5-trimethoxy-3-methylbenzylidene)piperazine-2,5-dione 

Relevant articles and documents

Preparation of chiral right-half models of antitumor bistetrahydroisoquinolinequinone natural products

– The preparation of chiral right-half model compounds of bistetrahydroisoquinolinequinone natural products having a lactam carbonyl group (-)-1 or an aminonitrile group (+)-2 from (-)-14 was presented. The crucial steps of this synthesis include the N-methylation of compound (-)-12 and ring closure to generate (-)-19a without any epimerization at C-2.1