19374-73-3

Basic information

• Product Name: 9-phenyl-10,9-oxaboraphenanthrene
• Synonyms: 9-phenyl-10,9-oxaboraphenanthrene
• CAS NO: 19374-73-3
• Molecular Weight: 256.112
• Mol File: 19374-73-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9-phenyl-10,9-oxaboraphenanthrene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-phenyl-10,9-oxaboraphenanthrene(19374-73-3)
• EPA Substance Registry System: 9-phenyl-10,9-oxaboraphenanthrene(19374-73-3)

Safety Data

• Hazardous Substances Data: 19374-73-3(Hazardous Substances Data)

Upstream product

• 19091-73-7 9-chloro-9-bora-10-oxa-phenanthrene 
• 533-58-4 2-Iodophenol 
• 3677-81-4 diphenylboronchloride 
• 591-51-5 phenyllithium 
• 100-58-3 phenylmagnesium bromide 
• 98882-69-0 diphenyl-propoxy-borane 
• 13188-39-1 B,B-diphenyl-boranylamine 
• 1623-99-0 phenyl sodium 
• 960-71-4 triphenylborane 
• 7397-50-4 diphenyl(diethylamino)borane 
• 873-51-8 phenylborondichloride 
• 100-56-1 phenylmercury(II) chloride 
• 591-50-4 iodobenzene 
• 15323-04-3 diphenylborinic acid butyl ester 

Relevant articles and documents

10,9-Oxaboraphenanthrenes as luminescent fluorophores

Reactions of 9-chloro-10,9-oxaboraphenanthrene (1) with the phenyl-, p-tolyl-, m-xylyl-, mesityl-, 2,4,6-tri-iso-propylphenyl-, 3,5-bis(trifluoromethyl)phenyl-, and pentafluorophenyl-Grignard reagents resulted in the formation of the corresponding oxaboraphenanthrene derivatives namely 9-phenyl- (2), 9-p-tolyl- (3), 9-(3,5-dimethylphenyl)- (9-m-xylyl-) (4), 9-mesityl- (5), 9-(2,4,6-tri-iso-propylphenyl)- (6), 9-(3,5-bis(trifluoromethyl)phenyl)- (7), and 9-(pentafluorophenyl)-10,9-oxaboraphenanthrene (8). 9-Trisyl- (9) and 9-supersilyl-10,9-oxaboraphenanthrene (10) were obtained selectively employing 1 and Li[C(SiMe3)3] or Na[SitBu3] as reactants. The compounds 4-9 were characterized by X-ray crystallography. The fluorescence measurements of 5-9 embedded in PMMA show emission bands with λmaxfrom 341 to 373 nm.