193748-82-2Relevant academic research and scientific papers
Synthesis and X-ray crystal structures of silacalix[n]phosphinines: The first sp2-based phosphorus macrocycles
Avarvari, Narcis,Maigrot, Nicole,Ricard, Louis,Mathey, Francois,Le Floch, Pascal
, p. 2109 - 2118 (2007/10/03)
The synthesis of silacalix[n]-phosphinines (n=3, 4)is presented. Three strategies have been investigated. Firstly, the thermal condensation of one equivalent of a 1,3,2-diazaphosphinine 1 with one equivalent of the diyne (PhCC)2SiMe2
New carbon-phosphorus macrocycles
Mathey, Francois,Mercier, Francois,Le Floch, Pascal
, p. 251 - 256 (2007/10/03)
The synthesis of several phosphole and phosphinine-based macrocycles is described The first ones are flexible as a result of the low inversion barrier of phosphorus. The mixture of isomers can be directly used in coordination chemistry. The second ones ar
