193812-91-8

Upstream product

• 576-22-7 2-Bromo-m-xylene 
• 22433-91-6 2-bromoisophthalic acid 
• 174833-49-9 2-bromo-1,3-diacetylbenzene 
• 151603-30-4 2-bromobenzene-1,3-dicarboxylic acid dichloride 

Downstream Products

• 193812-92-9 (2-Bromo-3-cyclopropanecarbonyl-phenyl)-cyclopropyl-methanone 
• 1292781-17-9 2,6-bis(2-methyloxazol-4-yl)bromobenzene 
• 1292781-21-5 C₁₂H₉Br₂NO₂ 
• 1292781-18-0 2-(2-methylthiazole-4-yl)-6-(2-methyloxazole-4-yl)bromobenzene 
• 1415039-59-6 1-bromo-2,6-bis(2-methylthiazol-4-yl)benzene 
• 193812-90-7 C₂₈H₃₄O₄Se₂ 
• 193812-96-3 (4S,5R)-4-((S)-2,6-Ditetrahydro-furan-2-yl-phenylselanyl)-5-phenyl-dihydro-furan-2-one 
• 193812-94-1 C₁₄H₁₇BrO₂ 
• 193812-93-0 1-[2-Bromo-3-(4-chloro-butyryl)-phenyl]-4-chloro-butan-1-one 

Relevant academic research and scientific papers

Novel bis(azole) pincer palladium complexes: Synthesis, structures and applications in Mizoroki-Heck reactions

Two novel NCN-pincer complex precursors bearing frameworks of 2,6-bis(oxazol-4-yl)benzene (A) and 2-(thiazol-4-yl)-6-(oxazol-4-yl)benzene (B) were synthesized. Palladations of A and B afforded two new bis(azole) pincer complexes, [(A-κ3NCN)PdBr] (1) and [(B-κ3NCN) PdBr] (2). Both complexes were fully characterized by NMR, MS, DSC-TGA and single-crystal X-ray diffraction analysis. Complex 1 crystallizes in a noncentrosymmetric orthorhombic space group Cmc21 (No. 36, Z = 4). Complex 2 crystallizes in a centrosymmetric monoclinic space group P2 1/n (No. 14, Z = 4). Despite the similarity in their chemical formulas, the structures of the two complexes are subtly different: they are built up of two-dimensional supramolecular layers with identical topology, but stacked in different sequences, i.e., the layers in complex 1 are stacked in an AAAA-type fashion, while those in complex 2 are stacked in an alternating AA-1AA-1 sequence (A denotes a layer; A-1 stands for A's inversion symmetry equivalent). In addition, the complexes showed good catalytic activity toward Mizoroki-Heck reactions. The Royal Society of Chemistry 2011.

2,6-bis[(2S)-tetrahydrofuran-2-yl]phenyl diselenide: An effective reagent for asymmetric electrophilic addition reactions to olefins

The enantioselective synthesis of a new and extremely effective organoselenium reagent (2) is reported. This chiral reagent was found to react with alkenes with a very high degree of facial selectivity in selenomethoxylation and ring closure reactions. In some cases the diastereoselectivities were found to be as high as 98%.