193977-54-7

Upstream product

• 963-15-5 (Z)-1,2-bis(phenylsulfonyl)ethene 
• 193977-53-6 (4S,5S)-5-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-8-(4-methoxy-benzyloxy)-octan-4-ol 
• 119649-27-3 4-((4-methoxybenzyl)oxy)butanal 
• 193977-51-4 (E)-8-(4-Methoxy-benzyloxy)-oct-4-enoic acid ethyl ester 
• 154476-70-7 6-(4-methoxybenzyloxy)hex-1-en-3-ol 

Downstream Products

• 193977-55-8 (4S,5S)-4-((Z)-2-Benzenesulfonyl-vinyloxy)-5-benzyloxy-8-(4-methoxy-benzyloxy)-octaneselenoic acid Se-phenyl ester 

Relevant academic research and scientific papers

Stereoselective synthesis of the 2,6-disubstituted tetrahydropyran-3-ol of the potent antitumor agent mucocin via an acyl radical cyclization

The intramolecular acyl radical cyclization of the acyl selenide 8, using a Z-vinylogous sulfonate to control rotamer population, affords the cis-2,6-disubstituted tetrahydropyran-4-one 9, applicable to the potent antitumor agent mucocin 1 in 81% yield.