19423-85-9

Usage

Uses

Used in Chemical Synthesis:
Erbium Chloride Hydrate, 99.997%, is used as a mild Lewis acid for selective acetalization, enabling the formation of specific chemical compounds with desired properties.
Used in Reducing Agents:
Erbium Chloride Hydrate, 99.997%, is used in combination with sodium borohydride as a selective reducing agent, facilitating the reduction of specific functional groups in chemical reactions.
Used in Enolate Formation:
Erbium Chloride Hydrate, 99.997%, is used to form enolates from alpha-bromo ketones, which are important intermediates in organic synthesis.
Used in Oxyallyl Cation Formation:
Erbium Chloride Hydrate, 99.997%, is used to generate oxyallyl cations from alpha, alpha'-dibromo ketones, which are useful in various organic transformations.

Upstream product

• 7647-01-0 hydrogenchloride 
• 7732-18-5 water 

Downstream Products

• 109181-42-2 (ErCl₂(((H₃C)2N)3PO)4)⁽¹⁺⁾*B(C₆H₅)4^(1-)=(ErCl₂(((H₃C)2N)3PO)4)(B(C₆H₅)4) 
• 114363-89-2 ErCl₃*H₂O 
• 1261477-33-1 ((HSC₆H₄NHCOCH₂NCH₂COOC₂H₄)2NCH₂COO)Er 

Relevant academic research and scientific papers

Magnetic relaxation behavior of lanthanide substituted Dawson-type tungstoarsenates

Two new polyoxometalate compounds [(CH3)4N]8[Ln(H2O)8]2[(α2-As2W17O61)Ln(H2O)2]2·nH2O (Ln=Er (1), Dy (2)) have been prepared by the trivacant Dawson-type anion [α-As2W15O56]12- and trivalent rare earth ion and characterized by single-crystal X-ray diffraction, IR spectra, thermogravimetric and electrochemical analyses. The centrosymmetric polyoxoanion, {[(α2-As2W17O61)Ln(H2O)2]2}14-, bounded to each other via Ln3+ connecting to terminal W-O oxygen atoms. Furthermore, the polyoxoanions are linked by [Ln(H2O)8]3+ to form an extensive 3D supramolecular network structure depending on hydrogen bond. The magnetic properties of the two compounds have been studied by measuring their magnetic susceptibilities in the temperature range 2.0-300.0 K, indicating the depopulation of the stark components at low temperature and/or very weak antiferromagnetic interactions between magnetic centers. Low-temperature ac magnetic susceptibility measurements reveal a slow magnetic relaxation behavior for 2.

Synthesis and structure of dimeric anthracene-9-carboxylato bridged dinuclear erbium(III) complex, [Er2(9-AC)6(DMF)2(H2O)2]

We study the influence of the bulky aromatic rings, e.g. anthracence-9-carboxylic acid (9-ACA) with a large conjugated π-system on the structure and spectroscopic properties of [Er2(9-AC)6(DMF)2(H2O)2

Synthesis and structural characterization of nonanuclear lanthanide complexes

A series of nonanuclear lanthanide oxo-hydroxo complexes of the general formula [Ln9(μ4-O)2 (μ3-OH)8(μ-BA)8- (BA)8]-[HN(CH2 CH3)3]+· (CH3OH)2(CHCl3) (BA = benzoylacetone; Ln = Sm, 1; Eu, 2; Gd, 3; Dy, 4; Er, 5) were prepared by the reaction of hydrous lanthanide trichlorides with benzoylacetone in the presence of triethylamine in methanol and recrystallized from chloroform/methanol (1:10) at room temperature. These five compounds are isomorphous. Crystal data for 1: cubic, Pn3n; T = 180 K; a = 33.8652(4) A; V = 38838.4(8) A3; Z = 6; Dcalcd = 1.125 g cm-3; R1 = 3.37%. Crystal data for 2: cubic, Pn3n; T = 180 K; a = 33.8252(8) A; V = 38700.9(16) A3; Z = 6; Dcalcd = 1.133 g cm-3; R1 = 4.97%. Crystal data for 3: cubic, Pn3n; T = 180 K; a = 33.7061(6) A; V = 38293.5(12) A3; Z = 6; Dcalcd = 1.157 g cm-3; R1 = 5.13%. Crystal data for 4: cubic, Pn3n; T = 180 K; a = 33.5900(7) A; V = 37899.2(14) A3; Z = 6; Dcalcd = 1.182 g cm-3; R1 = 4.03%. Crystal data for 5: cubic, Pn3n; T = 180 K; a = 33.5054(8) A; V = 37613.6(16) A3; Z = 6; Dcalcd = 1.202 g cm-3; R1 = 4.86%. The core of the anionic cluster comprises two vertex-sharing square-pyramidal [Ln5(μ4-O)(μ3- OH)4]9+ units. The compounds were characterized by elemental analysis, IR, fast atom bombardment mass spectra, thermogravimetry, and differential scanning calorimetry. The thermal analysis indicated that the nonanuclear species were stable up to 150 °C. Luminescence spectra of 2 and magnetic properties of 1-5 were also studied.

Synthesis of Er-complexes for photonic applications

We present a new approach of introducing erbium ions onto thin surface layers of silica glass substrates based on soaking of solution of erbium complexes. Different types of Er3+ complexes with 2,2′-dipyridyle, 1,10-phenantroline, 8-hydroxyquinoline and ethylendiamine ligands and nitrate, thiocyanate and acetate anions were prepared. Composition of the complexes was determined by elementary analysis and by FT-IR spectroscopy. Decomposition temperature was measured by thermogravimetric analysis. Erbium doped surface layers exhibit strong photoluminescence with maximum on 1533 nm and full width at half maximum above 50 nm.

catena-Poly[[bis[pentaaqua-erbium(III)]-μ-benzenehexacarboxylato] tetrahydrate]

The title compound is composed of one-dimensional polymeric {[Er2(C12O12)(H2O)10] ·4H2O}n chains containing Er in a slightly distorted antiprismatic eightfold coordination. The benzenehexacarboxylate ion is located about an inversion centre. Water molecules of crystallization, linked by hydrogen bonding to water molecules of the rare earth coordination spheres or the carboxylate groups of the organic ligands, fill the space generated by the packing of the separated chains.

Investigation of desolvation process in lanthanide dinicotinates

The desolvation process in lanthanide pyridine-3,5-dicarboxylates of the formulae [Tb2pdc3(dmf)2]?dmf (1), [Ho 2pdc3(dmf)2]?dmf (2), [Erdc 3(dmf)2]?dmf (3), and [Yb2pdc 3(dmf)2]?dmf (4) where pdc-C5H 3N(COO) 2 2-, dmf-N,N′-dimethylformamide) has been investigated by means of the TG-DSC, TG-FTIR, IR and XRD methods. Heating of the complexes in the range 30-260 °C lead to evolution of weakly bonded dmf molecules included in the channels as well those directly bonded with lanthanide atoms. The kinetic analysis revealed a multistep desolvation pattern.

Optical properties of single crystals of heavy lanthanide chlorides

Studies of heavy lanthanide chlorides may provide important information on the degree of Ln3+-ligand bond covalency. Monocrystals of LnCl3·6H2O, where Ln = Dy, Ho and Er, were grown and spectroscopic investigations were pe

Synthesis, structure, thermal and luminescent behaviors of lanthanide-Pyridine-3,5-dicarboxylate frameworks series

The isostructural series of lanthanide pyridine-3,5-dicarboxylates of the formula [Ln2pdc3(dmf)2]·(dmf) x(H2O)y where Ln are lanthanides from La(III) to Lu(III); pdc2--C5/s

Near-infrared luminescence from visible-light-sensitized hybrid materials covalently linked with tris(8-hydroxyquinolinate)-lanthanide [Er(III), Nd(III), and Yb(III)] derivatives

A series of new near-infrared (NIR) luminescent lanthanide-quinolinate derivatives [Ln(Q-Si)3] and xerogels (named as LnQSi-Gel, Ln = Er, Nd, Yb) covalently linked with the Ln(Q-Si)3 by using the 8-hydroxyquinoline-functionalized alkoxysilane (Q-Si) have been synthesized. The obtained xerogel materials LnQSi-Gel are rigid and show homogeneous by field-emission scanning electron microscopy (FE-SEM) images. The Fourier-transform infrared (FT-IR), fluorescence spectra of Ln(Q-Si) 3, and LnQSi-Gel were measured, and the corresponding luminescence decay analyses were recorded. Of importance here is that the excitation spectra of the Ln(Q-Si)3 and LnQSi-Gel extend to the region of visible light (more than 500 nm). Upon ligand-mediated excitation with the visible light, the Ln(Q-Si)3 and LnQSi-Gel show the characteristic NIR-luminescence of the corresponding lanthanide ions through the intramolecular energy transfer from the ligands to the lanthanide ions. The good luminescent performances enable these NIR-luminescent xerogel materials to have possible applications in medical diagnostics, laser systems, and optics, etc.

Syntheses and characterization of novel lanthanide adamantine-dicarboxylate coordination complexes

Hydrothermal reactions of 1,10-phenanthroline (phen), 1,3-adamantanedicarboxylic acid (H2L) and lanthanide chlorides yielded six compounds: [Ln(L)(HL)(phen)] (Ln=Pr, 1; Nd, 2), [Ln(L)(HL)(phen)(H2O)] (Sm, 3; Eu, 4), [Tb(L)(HL)(phen)(