194342-89-7

Basic information

• Product Name: (2R,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-10-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-one
• Synonyms: (2R,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-10-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-one
• CAS NO: 194342-89-7
• Molecular Weight: 663.721
• Mol File: 194342-89-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-10-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-10-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-one(194342-89-7)
• EPA Substance Registry System: (2R,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-10-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undecan-4-one(194342-89-7)

Safety Data

• Hazardous Substances Data: 194342-89-7(Hazardous Substances Data)

Upstream product

• 194342-75-1 (4S,6S)-8-(2-Bromo-benzyloxy)-4-(tert-butyl-dimethyl-silanyloxy)-6-(tetrahydro-pyran-2-yloxy)-octan-2-one 
• 194342-86-4 Acetic acid (2R,4S,6R,8S,10S)-8-[2-(2-bromo-benzyloxy)-ethyl]-10-hydroxy-2-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undec-4-yl ester 
• 194342-94-4 (3S,5S)-7-(2-Bromo-benzyloxy)-3-hydroxy-1-((S)-4-isopropyl-2-thioxo-thiazolidin-3-yl)-5-(tetrahydro-pyran-2-yloxy)-heptan-1-one 
• 194342-83-1 (3S,5S)-7-(2-Bromo-benzyloxy)-3-hydroxy-5-(tetrahydro-pyran-2-yloxy)-heptanoic acid methoxy-methyl-amide 
• 194342-82-0 (S)-5-(2-Bromo-benzyloxy)-3-(tetrahydro-pyran-2-yloxy)-pentanoic acid methoxy-methyl-amide 
• 194342-72-8 (S)-5-(2-Bromo-benzyloxy)-3-hydroxy-1-((S)-4-isopropyl-2-thioxo-thiazolidin-3-yl)-pentan-1-one 
• 194342-74-0 (S)-5-(2-Bromo-benzyloxy)-3-(tetrahydro-pyran-2-yloxy)-pentanal 
• 194342-73-9 (S)-5-(2-Bromo-benzyloxy)-3-hydroxy-pentanoic acid methoxy-methyl-amide 
• 194342-76-2 (3R)-4-(4-methoxybenzyloxy)-3-(tetrahydro-2H-pyran-2-yl)oxybutanal 
• 194342-85-3 2-[(R)-1-(4-Methoxy-benzyloxymethyl)-but-3-enyloxy]-tetrahydro-pyran 
• 194342-84-2 (R)-1-[(4-methoxybenzyl)oxy]pent-4-en-2-ol 
• 194342-71-7 3-(2-Bromo-benzyloxy)-propionaldehyde 
• 194342-70-6 3-((2-bromobenzyl)oxy)propan-1-ol 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 194342-92-2 (2R,4S,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-4,10-bis-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxymethyl)-4-methyl-1,7-dioxa-spiro[5.5]undecane 
• 194342-79-5 (2R,4S,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-10-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxymethyl)-4-methyl-1,7-dioxa-spiro[5.5]undecan-4-ol 

Relevant articles and documents

A modular approach to marine macrolide construction. 1. An enantiocontrolled route to the C1-C12 (AB) spiroacetal sector

A practical approach to a desymmetrized, enantiomerically pure AB spiroacetal ring component of altohyrtin A and its congeners is detailed.